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Merck

36323

Sigma-Aldrich

(S)-2-哌啶酮-6-羧酸

≥95.0% (HPLC)

别名:

6-氧代-L-哌啶甲酸, (S)-2-哌啶酮-6-甲酸, L-Pyrohomoglutamic acid

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About This Item

经验公式(希尔记法):
C6H9NO3
CAS号:
分子量:
143.14
MDL號碼:
分類程式碼代碼:
12352005
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

≥95.0% (HPLC)

雜質

≤5.0% water

SMILES 字串

OC(=O)[C@@H]1CCCC(=O)N1

InChI

1S/C6H9NO3/c8-5-3-1-2-4(7-5)6(9)10/h4H,1-3H2,(H,7,8)(H,9,10)/t4-/m0/s1

InChI 密鑰

FZXCPFJMYOQZCA-BYPYZUCNSA-N

應用

(S)-6-Oxo-2-piperidinecarboxylic acid can be used as a reactant to synthesize:
  • Functionalized β-lactam N-heterocycles via carboxymethylproline synthase catalyzed cyclization reactions. Pro-(S)-C5 branched [4.3.1] aza-amide bicycles as potential inhibitors for FK506-binding proteins.
  • Ethyl (S)-2-(6-oxopiperidin-2-yl)acetate, which is reduced using LiBH4 to produce optically pure hydroxymethyl lactams.

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 2

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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分析证书(COA)

Lot/Batch Number

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访问文档库

Carboxymethylproline synthase catalysed syntheses of functionalised N-heterocycles
Hamed RB, et al.
Chemical Communications (Cambridge, England), 46(9), 1413-1415 (2010)
Preparation of optically pure ω-hydroxymethyl lactams
Huang S-B, et al.
Synthetic Communications, 19(20), 3485-3496 (1989)
Rational Design and Asymmetric Synthesis of Potent and Neurotrophic Ligands for FK506-Binding Proteins (FKBPs)
Pomplun S, et al.
Angewandte Chemie (International ed. in English), 54(1), 345-348 (2015)

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