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Merck

34850-M

Sigma-Aldrich

丙酮

suitable for HPLC, ≥99.8%

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About This Item

线性分子式:
CH3COCH3
CAS号:
分子量:
58.08
Beilstein:
635680
EC號碼:
MDL號碼:
分類程式碼代碼:
12190000
eCl@ss:
39021201
PubChem物質ID:
NACRES:
NA.02

等級

HPLC grade

蒸汽密度

2 (vs air)

蒸汽壓力

184 mmHg ( 20 °C)

化驗

≥99.8%

形狀

liquid

自燃溫度

465 °C (869 °F)

expl. lim.

13.2 %

技術

HPLC: suitable

雜質

≤0.0005% non-volatile matter
≤0.002% free acid (as CH3COOH)
≤0.1% water (Karl Fischer)

透射率

330 nm, ≥15%
335 nm, ≥50%
340 nm, ≥80%
350 nm, ≥98%

折射率

n20/D 1.359 (lit.)

pH值

(5 - 6 at 395 g/l at 20 °C (68 °F))

bp

56 °C/760 mmHg (lit.)

mp

−94 °C (lit.)

溶解度

water: miscible

密度

0.791 g/mL at 25 °C (lit.)

應用

general analytical

格式

neat

SMILES 字串

CC(C)=O

InChI

1S/C3H6O/c1-3(2)4/h1-2H3

InChI 密鑰

CSCPPACGZOOCGX-UHFFFAOYSA-N

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一般說明

Mixtures of TiO2 (P25) with rare earth oxides (La2O3 or Y2O3) calcined at 700°C or 650°C efficiently causes oxidation of acetone. Its Aldol condensation in vapor-phase has been investigated over MgO promoted with alkali (Li, Na, K and Cs) or alkaline earth (Ca, Sr and Ba) metal ions. It undergoes Aldol condensation in the presence of Mg-Al layered double hydroxides (LDH) as catalysts and Cl- and/or CO32- as compensating anions to afford diacetone alcohol and mesityl oxide. Enantioselective Aldol condensation of acetone with various isatins in the presence of dipeptides (catalyst) has been described.

應用

丙酮的发光强度取决于溶液组分。丙酮吸收UV光,导致丙酮光分解和放射性产物。
Acetone has been used in the preparation of 13wt% amorphous poly (lactic acid) (PLA) solution, which was required for the preparation of electrospun PLA membranes.

包裝

其他說明

Important notice
  • The article number 34850-4X2.5L-M will be discontinued. Please order the single bottle 34850-2.5L-M which is physically identical with the same exact specifications.
  • The article number 34850-6X1L-M will be discontinued. Please order the single bottle 34850-1L-M which is physically identical with the same exact specifications.

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訊號詞

Danger

危險聲明

危險分類

Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

標靶器官

Central nervous system

安全危害

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

1.4 °F - closed cup

閃點(°C)

-17.00 °C - closed cup


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Gianluigi Luppi et al.
The Journal of organic chemistry, 70(18), 7418-7421 (2005-08-27)
[reaction: see text] The aldol condensation of acetone with several isatins is described. The desired compound was obtained in quantitative yield and with good enantioselectivities up to 77%. The best results were obtained with 10 mol % H-D-Pro-L-beta3-hPhg-OBn as a

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