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Merck

33801

Sigma-Aldrich

L-(+)-酒石酸

puriss. p.a., reag. ISO, 99.5-101.0% (calc. to the dried substance)

别名:

(2R,3R)-(+)-酒石酸, 左旋酒石酸

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About This Item

线性分子式:
HO2CCH(OH)CH(OH)CO2H
CAS号:
分子量:
150.09
Beilstein:
1725147
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.21

Agency

Ph. Eur.
USP/NF
reag. ISO

质量水平

蒸汽密度

5.18 (vs air)

等级

puriss. p.a.

方案

99.5-101.0% (calc. to the dried substance)

表单

powder or crystals

旋光性

[α]20/D +12.0 to +12.8°, c = 20% in H2O

自燃温度

797 °F

杂质

≤0.0005% heavy metals (as Pb)

灼烧残渣

≤0.1% (as SO4)

缺失

≤0.1% loss on drying, 105 °C

mp

170-172 °C (lit.)

痕量阴离子

chloride (Cl-): ≤5 mg/kg
phosphate (PO43-): ≤10 mg/kg
sulfate (SO42-): ≤150 mg/kg

痕量阳离子

Ca: ≤20 mg/kg
Cu: ≤5 mg/kg
Fe: ≤5 mg/kg
Pb: ≤2 mg/kg
Zn: ≤5 mg/kg

SMILES字符串

O[C@H]([C@@H](O)C(O)=O)C(O)=O

InChI

1S/C4H6O6/c5-1(3(7)8)2(6)4(9)10/h1-2,5-6H,(H,7,8)(H,9,10)/t1-,2-/m1/s1

InChI key

FEWJPZIEWOKRBE-JCYAYHJZSA-N

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相关类别

一般描述

L-(+)-Tartaric acid is an organic acid naturally found in grapes and wines. It is widely used as flavoring agent and antioxidizing agent for various beverages (grape juices and wines). It can be synthesized starting from L-ascorbic acid (AA, vitamin C). Its forms various hydrogen-L-tartrate salts, which have important applications in crystal engineering studies. Its quantification in grape juice has been carried out by recording HPLC chromatograms.

应用

L-(+)-Tartaric acid may be employed as starting reagent in the synthesis of enantiomeric forms of pyrrolidinoisoquinoline derivatives.

象形图

Corrosion

警示用语:

Danger

危险声明

预防措施声明

危险分类

Eye Dam. 1

储存分类代码

11 - Combustible Solids

WGK

WGK 1

闪点(°F)

302.0 °F - closed cup

闪点(°C)

150 °C - closed cup

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Organic salts of L-tartaric acid: materials for second harmonic generation with a crystal structure governed by an anionic hydrogen-bonded network.
Aakeroy CB, et al.
Journal of the Chemical Society. Chemical Communications, 7, 553-555 (1992)
Organic acid profile of Turkish white grapes and grape juices.
Soyer Y, et al.
J. Food Compos. Anal., 16(5), 629-636 (2003)
Asymmetric synthesis of both enantiomers of pyrrolidinoisoquinoline derivatives from L-malic acid and L-tartaric acid.
Lee YS, et al.
The Journal of Organic Chemistry, 60(22), 7149-7152 (1955)
Seth DeBolt et al.
Proceedings of the National Academy of Sciences of the United States of America, 103(14), 5608-5613 (2006-03-29)
The biosynthetic pathway of L-tartaric acid, the form most commonly encountered in nature, and its catabolic ties to vitamin C, remain a challenge to plant scientists. Vitamin C and L-tartaric acid are plant-derived metabolites with intrinsic human value. In contrast
J B Olivato et al.
Carbohydrate polymers, 92(2), 1705-1710 (2013-02-13)
Tartaric acid (TA), a dicarboxylic acid, can act as a compatibiliser in starch/polyester blends. A mixture design was proposed to evaluate the effect of TA on the properties of starch/poly (butylene adipate co-terephthalate) (PBAT) blown films plasticised with glycerol. The

实验方案

Silica gel G 254 plates are suitable for analysis of Dextromethorphan following the European pharmacopeia monograph.

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