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Merck
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文件

685569

Sigma-Aldrich

(11bS)-N,N-二甲基-8,9,10,11,12,13,14,15-八氢二萘并[2,1-d:1′,2′-f][1,3,2]二噁磷杂庚英-4-胺

别名:

MonoPhos Ligand

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About This Item

经验公式（希尔记法）:
C22H26NO2P
CAS号:
389130-06-7
分子量:
367.42
MDL號碼:
MFCD04117692
分類程式碼代碼:
12352005
PubChem物質ID:
329760980
NACRES:
NA.22

形狀

solid

光學活性

[α]22/D 282.0°, c = 1 in chloroform

mp

86-94 °C

SMILES 字串

CN(C)P1Oc2ccc3CCCCc3c2-c4c(O1)ccc5CCCCc45

InChI

1S/C22H26NO2P/c1-23(2)26-24-19-13-11-15-7-3-5-9-17(15)21(19)22-18-10-6-4-8-16(18)12-14-20(22)25-26/h11-14H,3-10H2,1-2H3

InChI 密鑰

OIZQADYWBXZQKE-UHFFFAOYSA-N

相关类别

應用

DSM MonoPhos Family of Highly Efficient Privileged Ligands
(11bS)-N,N-dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine is a monodentate phosphoramidite (MonoPhos) chiral ligand that can be used:
  • In the Cu-catalyzed synthesis of chiral 3-(arylbut-1-yn-1-yl)silane derivatives by reacting N-tosylhydrazones with silyl-substituted alkynes via asymmetric insertion.
  • In the Rh-catalyzed asymmetric hydrogenation of R-isopropylcinnamic acid derivative, a key intermediate of renin inhibitor aliskiren.
  • In the Rh-catalyzed conjugate addition of arylboronic acids to lactones, enones, and nitroalkenes.

法律資訊

经 DSM 授权销售，仅供研究之用。

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)

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A mixed-ligand approach enables the asymmetric hydrogenation of an α-isopropylcinnamic acid en route to the renin inhibitor aliskiren
Boogers JAF, et al.
Organic Process Research & Development, 11(3), 585-591 (2007)
Asymmetric Copper-Catalyzed C (sp)-H Bond Insertion of Carbenoids Derived from N-Tosylhydrazones
Osako T, et al.
Synlett, 29(17), 2251-2256 (2018)
Rhodium-catalyzed asymmetric conjugate additions of boronic acids using monodentate phosphoramidite ligands
Boiteau J, et al.
Organic Letters, 5(5), 681-684 (2003)

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