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化驗
95% (HPLC)
mp
102-103 °C
SMILES 字串
C[C@@H](N([C@H](C)c1ccccc1)P2Oc3ccc4ccccc4c3-c5c(O2)ccc6ccccc56)c7ccccc7
InChI
1S/C36H30NO2P/c1-25(27-13-5-3-6-14-27)37(26(2)28-15-7-4-8-16-28)40-38-33-23-21-29-17-9-11-19-31(29)35(33)36-32-20-12-10-18-30(32)22-24-34(36)39-40/h3-26H,1-2H3/t25-,26-/m1/s1
InChI 密鑰
LKZPDRCMCSBQFN-CLJLJLNGSA-N
應用
手性亚磷酰胺配体,用于铜催化的高对映选择性共轭加成反应,该反应可将二烷基锌加成到各种 Michael 受体。也可用于二乙基锌介导的钯催化极性反转烯丙基化反应。
特點和優勢
Advantages of the MonoPhos® ligands:
- Superior enantiocontrol in numerous transformations
- High activities at low catalyst loadings
- Hydrogenations under low-pressure conditions
法律資訊
经 DSM 授权销售,仅供研究使用。
MonoPhos is a registered trademark of DSM IP Assets B.V.
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
其他客户在看
Privileged Ligands
Aldrich Chemfiles, 6(8), 7-7 null
Organic & Biomolecular Chemistry, 4, 1278-1278 (2006)
Synlett, 1375-1375 (2001)
Organic letters, 4(22), 3835-3837 (2003-02-26)
[formula: see text] The zinc enolates, resulting from the copper-catalyzed enantioselective conjugate addition of dialkyl zinc reagents to cyclic and acyclic enones, could be trapped, quantitatively, as silyl enol ethers with TMSOTf in apolar solvents or with TMSCI and NEt3.
The Journal of organic chemistry, 70(18), 7451-7454 (2005-08-27)
[reaction: see text] The enantioselective catalytic 1,4-addition to alpha,beta-unsaturated ketimines is an unprecedented process. Herein, we document the copper-catalyzed addition of dialkylzinc reagents to (2-pyridylsulfonyl)imines of chalcones. This process occurs rapidly in the presence of a chiral phosphoramidite ligand to
商品
DSM collaboration offers MonoPhos™ ligands for research, based on the BINOL platform by Feringa and co-workers.
我们的科学家团队拥有各种研究领域经验,包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
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