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Merck

499552

Sigma-Aldrich

锌 制备

5 g/dL Zn+2 in THF, highly reactive Rieke®metal

别名:

Zn

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About This Item

线性分子式:
Zn
CAS号:
分子量:
65.39
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22

质量水平

反应适用性

core: zinc
reagent type: catalyst

浓度

5 g/dL Zn+2 in THF

密度

0.949 g/mL at 25 °C

储存温度

2-8°C

SMILES字符串

[Zn]

InChI

1S/Zn

InChI key

HCHKCACWOHOZIP-UHFFFAOYSA-N

应用

Rieke®锌可用于还原常见有机官能团,如芳硝基化合物、共轭醛、芳炔和苯丙炔酸酯。

法律信息

Rieke Metals, Inc.公司产品。
Rieke 是Rieke Metals, Inc.公司的注册商标。
Rieke is a registered trademark of Rieke Metals, Inc.

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

靶器官

Central nervous system, Respiratory system

补充剂危害

储存分类代码

3 - Flammable liquids

WGK

WGK 2

闪点(°F)

1.0 °F - closed cup

闪点(°C)

-17.22 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Rieke zinc as a reducing agent for common organic functional groups
Kroemer J, et al.
Tetrahedron Letters, 47(36), 6339-6341 (2006)
Casper Groth et al.
Development (Cambridge, England), 140(14), 3018-3027 (2013-06-21)
Developmental patterning requires the precise interplay of numerous intercellular signaling pathways to ensure that cells are properly specified during tissue formation and organogenesis. The spatiotemporal function of the Notch signaling pathway is strongly influenced by the biosynthesis and intracellular trafficking
I A Popov et al.
Molekuliarnaia biologiia, 47(3), 498-504 (2013-07-31)
Alzheimer's disease, is a lethal neurodegenerative pathology, characterized by the formation of soluble neurotoxic oligomers of the human amyloid-beta peptide Abeta which get accumulated forming polymeric extracellular aggregates (so-called amyloid plaques). The isomerized at aspartate 7 isoform of the human
M E Kuyumcu et al.
European review for medical and pharmacological sciences, 17(11), 1467-1471 (2013-06-19)
Zinc is one of the most important elements for human body. Zinc deficiency can occur in any age, if it is seen in elderly its clinical results can be more harmful due to already diminished functions. Some studies showed zinc
Nalini Pandey et al.
Indian journal of experimental biology, 51(7), 548-555 (2013-08-01)
Black gram plants subjected to varying levels of Zn supply (0.01 to 10 microM Zn) showed optimum growth and dry matter yield in plants receiving 1 microM Zn. The dry matter yield of plants decreased in plants receiving 0.01 and

商品

Metal-enhanced organic synthesis via organometallic intermediates is a widely used preparative route for thousands of organic compounds.

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