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Merck
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文件

365246

Sigma-Aldrich

2-硝基苯基硒基氰酸酯

97.5%

别名:

1-硝基-2-硒基氰酸苯酯, 邻硝基苯基硒基氰化物, 邻硝基苯基硒基氰酸酯

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About This Item

线性分子式:
O2NC6H4SeCN
CAS号:
51694-22-5
分子量:
227.08
Beilstein:
1309777
EC號碼:
257-350-4
MDL號碼:
MFCD00043146
分類程式碼代碼:
12352100
PubChem物質ID:
24862498
NACRES:
NA.22

化驗

97.5%

mp

140-142 °C (lit.)

SMILES 字串

[O-][N+](=O)c1ccccc1[Se]C#N

InChI

1S/C7H4N2O2Se/c8-5-12-7-4-2-1-3-6(7)9(10)11/h1-4H

InChI 密鑰

LHBLJWULWKQRON-UHFFFAOYSA-N

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相关类别

一般說明

2-硝基苯基硒氰酸酯是一种发色团硒化合物。

應用

可使用 2-硝基苯基硒氰酸酯（ o -硝基苯基硒氰酸酯）：
  • 研究其与金属硫蛋白锌/硫醇盐簇发生反应的机制
  • 2,3-开环-5α-胆甾烷-2,3-二醇制备过程中
  • 4α-甲基-2,3-开环-5α-胆甾烷-2,3-二醇制备过程中
  • 2-硝基苯硒基衍生物制备过程中
  • 3α-[（2-硝基苯基）硒] 雄甾-1,5-二烯-17β-ol合成过程中

訊號詞

Danger

危險分類

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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Shaoman Zhou et al.
Journal of medicinal chemistry, 49(20), 6120-6128 (2006-09-29)
All stereoisomers of adenine and guanine methylene-3-fluoromethylenecyclopropane analogues of nucleosides 9a, 9b, 10a, 10b, 11a, 11b, 12a, and 12b were synthesized and their antiviral activities were evaluated. A highly convergent approach permitted the synthesis of all these analogues using a
Synthesis and radical oxidation of steroidal 1-oxo-5α-alcohols.
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Zinc/thiolate (cysteine) coordination occurs in a very large number of proteins. These coordination sites are thermodynamically quite stable. Yet the redox chemistry of thiolate ligands confers extraordinary reactivities on these sites. The significance of such ligand-centered reactions is that they
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