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Merck

328502

Sigma-Aldrich

二甲基二硒醚

96%

别名:

甲基二硒

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About This Item

线性分子式:
(CH3)2Se2
CAS号:
分子量:
187.99
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

96%

形狀

liquid

折射率

n20/D 1.6388 (lit.)

bp

155-157 °C (lit.)

密度

1.987 g/mL at 25 °C (lit.)

SMILES 字串

C[Se][Se]C

InChI

1S/C2H6Se2/c1-3-4-2/h1-2H3

InChI 密鑰

VLXBWPOEOIIREY-UHFFFAOYSA-N

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一般說明

二甲基二硒醚是一种挥发性硒化合物,已报告用 HPLC-电感耦合氩等离子体质谱法测定生物样品中的二甲基二硒醚。用固相微萃取气相色谱-质谱法研究硒与二甲基二硒醚的烷基化反应。

應用

二甲基二硒醚是鉴定阳离子自由基最有效的试剂。

訊號詞

Danger

危險分類

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Flam. Liq. 3 - STOT RE 2

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

140.0 °F - closed cup

閃點(°C)

60 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Kathrin Schilling et al.
Journal of environmental quality, 40(3), 1021-1027 (2011-05-07)
If volatile organoselenides are to be analyzed for their stable Se isotope composition to elucidate sources and formation processes, organoselenides need to be trapped quantitatively to avoid artificial Se isotope fractionation. We developed an efficient trap of organoselenides to be
William J Hunter et al.
Journal of chromatography. A, 1038(1-2), 295-297 (2004-07-06)
A simple method for the determination of volatile selenium compounds employing a gas chromatograph equipped with a photoionization detector is described. The method involves the direct injection of dimethylselenide (DMS) or dimethyldiselenide (DMDS) into the gas chromatograph; no derivatization of
Elimination of selenium compounds by mice through formation of different volatile selenides.
S Jiang et al.
Experientia, 39(3), 293-294 (1983-03-15)
K K Thoen et al.
Journal of the American Society for Mass Spectrometry, 7(12), 1245-1250 (1996-12-01)
Dimethyl diselenide is demonstrated to be among the most powerful reagents used to identify distonic radical cations. Most such ions readily abstract CH3Se from dimethyl diselenide. The reaction is faster and more exclusive than CH3S(·) abstraction from dimethyl disulfide, a
Yiqiang Zhang et al.
Journal of environmental quality, 31(4), 1124-1128 (2002-08-15)
Volatilization of dimethyldiselenide (DMDSe) is one of the most important processes for removing selenium (Se) from Se-contaminated environments. However, the fate of DMDSe in soil is not known. In this study, we monitored the changes of DMDSe in the head

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