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Merck

230499

Sigma-Aldrich

硒脲

98%

别名:

2-硒脲, 异硒脲, 氨基亚硒酸, 硒脲

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About This Item

线性分子式:
NH2CSeNH2
CAS号:
分子量:
123.02
Beilstein:
1734744
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

98%

表单

solid

mp

210-215 °C (dec.)

官能团

amine

SMILES字符串

NC(N)=[Se]

InChI

1S/CH4N2Se/c2-1(3)4/h(H4,2,3,4)

InChI key

IYKVLICPFCEZOF-UHFFFAOYSA-N

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应用

Selenourea [(SeC(NH22)]已用作硒(Se)的前体,用于将Se插入蛋白质晶体中。
它也可作为试剂用于:
  • 从α-溴代酮合成硒唑(在β-环糊精存在下)。
  • 在氧化铜纳米颗粒作为催化剂的条件下,通过C-Se交叉偶联反应合成对称的二芳基硒化物。
  • 合成CdSe纳米晶体。

警示用语:

Danger

危险分类

Acute Tox. 2 Oral - Acute Tox. 3 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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A novel synthesis of CdSe nanocrystals
Epifani M, et al.
Materials Letters, 58(19), 2429-2432 (2004)
Sung Min Kwon et al.
Science advances, 4(4), eaap9104-eaap9104 (2018-04-18)
We report a general strategy for obtaining high-quality, large-area metal-chalcogenide semiconductor films from precursors combining chelated metal salts with chalcoureas or chalcoamides. Using conventional organic solvents, such precursors enable the expeditious formation of chalco-gels, which are easily transformed into the
B Mishra et al.
The journal of physical chemistry. B, 109(26), 12718-12723 (2006-07-21)
Reactions of biological oxidizing agents, such as hydroxyl radicals ((*)OH), singlet oxygen ((1)O(2)), hydrogen peroxide (H(2)O(2)), and peroxynitrite (ONOO(-)) with selenourea were studied. The kinetics of the reactions was followed using time-resolved techniques, and the bimolecular rate constants were determined.
K P Kalyanikutty et al.
Journal of nanoscience and nanotechnology, 7(6), 1916-1922 (2007-07-28)
Two-dimensional nanostructures in the form of ultra-thin crystalline films of CdSe and CuSe have been prepared at the organic-aqueous interface by reacting toluene solutions of metal cupferronates with an aqueous solution of N,N-dimethyl selenourea. The films have been examined using
B Mishra et al.
The journal of physical chemistry. A, 110(5), 1894-1900 (2006-02-03)
Pulse radiolysis coupled with absorption detection has been employed to study one-electron oxidation of selenomethionine (SeM), selenocystine (SeCys), methyl selenocysteine (MeSeCys), and selenourea (SeU) in aqueous solutions. Hydroxyl radicals (*OH) in the pH range from 1 to 7 and specific

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