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302473

Sigma-Aldrich

双环辛烯氯化铑二聚体

98%

别名:

[Rh(coe)2Cl]2

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About This Item

经验公式（希尔记法）:
C32H56Cl2Rh2
CAS号:
12279-09-3
分子量:
717.50
MDL编号:
MFCD00013287
UNSPSC代码:
12161600
PubChem化学物质编号:
24858255
NACRES:
NA.22

质量水平

100

方案

98%

表单

powder

反应适用性

core: rhodium
reagent type: catalyst

mp

190 °C (dec.) (lit.)

SMILES字符串

Cl[Rh].Cl[Rh].C1CCCC=CCC1.C2CCCC=CCC2.C3CCCC=CCC3.C4CCCC=CCC4

InChI

1S/4C8H14.2ClH.2Rh/c4*1-2-4-6-8-7-5-3-1;;;;/h4*1-2H,3-8H2;2*1H;;/q;;;;;;2*+1/p-2/b4*2-1-;;;;

InChI key

GQPAPAIPOLEZHT-XFCUKONHSA-L

相关类别

应用

双环辛烯氯化铑(I)二聚体可用作以下反应的催化剂：
  • 通过芳基硼酸与α,β-不饱和磺酰基化合物的不对称1,4-加成，合成富对映体的偕二芳基磺酸盐。
  • N脱保护吲哚和吡咯的直接C-芳基化。
  • 通过C-H键活化的在芳烃羧化反应。

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCV3539
MKCR7327
MKCQ3486
MKCP8266
MKCN0583

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Direct C-arylation of free (NH)-indoles and pyrroles catalyzed by Ar- Rh (III) complexes assembled in situ
Wang X, et al.
Journal of the American Chemical Society, 127(14), 4996-4997 (2005)
Chiral Phosphite-Olefin Ligands: Application in Rh-Catalyzed Asymmetric 1, 4-Addition of Arylboronic Acids to beta-Aryl-alpha, beta-unsaturated Sulfonates
Yue-Na Y and Ming-Hua X
Acta Chimica Sinica , 72(7), 815-819 (2014)
Jay A Labinger et al.
Nature, 417(6888), 507-514 (2002-05-31)
The selective transformation of ubiquitous but inert C H bonds to other functional groups has far-reaching practical implications, ranging from more efficient strategies for fine chemical synthesis to the replacement of current petrochemical feedstocks by less expensive and more readily
Ru-, Rh-, and Pd-catalyzed C-C bond formation involving C-H activation and addition on unsaturated substrates: reactions and mechanistic aspects.
Vincent Ritleng et al.
Chemical reviews, 102(5), 1731-1770 (2002-05-09)
Annulation of alkenyl-substituted heterocycles via rhodium-catalyzed intramolecular C-H activated coupling reactions.
K L Tan et al.
Journal of the American Chemical Society, 123(11), 2685-2686 (2001-07-18)
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