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Merck

272213

Sigma-Aldrich

环丙甲醛

98%

别名:

1-(甲酰基)环丙烷, 2-环丙烷甲醛, 环丙基甲醛, 环丙烷甲醛, 甲酰环丙烷

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About This Item

线性分子式:
C3H5CHO
CAS号:
分子量:
70.09
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
形狀:
liquid
化驗:
98%

品質等級

化驗

98%

形狀

liquid

折射率

n20/D 1.4298 (lit.)

bp

98-101 °C (lit.)

密度

0.938 g/mL at 25 °C (lit.)

官能基

aldehyde

儲存溫度

2-8°C

SMILES 字串

O=CC1CC1

InChI

1S/C4H6O/c5-3-4-1-2-4/h3-4H,1-2H2

InChI 密鑰

JMYVMOUINOAAPA-UHFFFAOYSA-N

相关类别

應用

环丙甲醛通过与[Ni(cod)(2)](cod = 1,5-环辛二烯)和PBu(3)反应,可合成eta(2)-烯酮镍配合物
用于制备环亚丙基四氢萘酮,其通过对映选择性钯催化的[3+2]TMM环加成反应,得到手性螺环稠合环戊烯。

象形圖

FlameCorrosion

訊號詞

Danger

危險聲明

危險分類

Flam. Liq. 2 - Skin Corr. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

44.6 °F - closed cup

閃點(°C)

7 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Wang, Z. et al
Tetrahedron Letters, 41, 4007-4007 (2000)
Barry M Trost et al.
Journal of the American Chemical Society, 128(41), 13328-13329 (2006-10-13)
Transition-metal-catalyzed trimethylenemethane (TMM) [3 + 2] cycloadditions provide direct routes to functionalized cyclopentanes. This reaction has been shown to be a highly chemo-, regio-, and diastereoselective process. We report a palladium-catalyzed asymmetric [3 + 2] trimethylenemethane (TMM) cycloaddition between 3-acetoxy-2-trimethylsilylmethyl-1-propene
M Cowart et al.
Bioorganic & medicinal chemistry letters, 11(1), 83-86 (2001-01-05)
The synthesis and SAR of a novel series of non-nucleoside pyridopyrimidine inhibitors of the enzyme adenosine kinase (AK) are described. It was found that pyridopyrimidines with a broad range of medium and large non-polar substituents at the 5-position potently inhibited
Krzysztof Z Łączkowski et al.
Medicinal chemistry research : an international journal for rapid communications on design and mechanisms of action of biologically active agents, 27(9), 2125-2140 (2018-09-18)
Synthesis and investigation of antifungal, anticonvulsant and anti-Toxoplasma gondii activities of ten novel (2-(cyclopropylmethylidene)hydrazinyl)thiazole 3a-3j are presented. Among the derivatives, compounds 3a-3d and 3f-3j possess very high activity against Candida spp. ATCC with MIC = 0.015-7.81 µg/ml. Compounds 3a-3d and 3f-3j possess also
Takashi Tamaki et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 15(39), 10083-10091 (2009-09-01)
Cyclopropanecarboxaldehyde (1 a), cyclopropyl methyl ketone (1 b), and cyclopropyl phenyl ketone (1 c) were reacted with [Ni(cod)(2)] (cod = 1,5-cyclooctadiene) and PBu(3) at 100 degrees C to give eta(2)-enonenickel complexes (2 a-c). In the presence of PCy(3) (Cy =

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