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Merck
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文件

206229

Sigma-Aldrich

氯化钌 (III) 水合物

ReagentPlus®

别名:

三氯化钌

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About This Item

线性分子式:
RuCl3 · xH2O
CAS号:
14898-67-0
分子量:
207.43 (anhydrous basis)
EC號碼:
233-167-5
MDL號碼:
MFCD00149844
分類程式碼代碼:
12352302
PubChem物質ID:
24852386
NACRES:
NA.23

品質等級

200

產品線

ReagentPlus®

形狀

powder and chunks

成份

Degree of hydration, ≤1
Ruthenium content, 40.00-49.00%

反應適用性

reagent type: catalyst
core: ruthenium

雜質

≤0.1% Insoluble matter (C=1%, 25% HCl)

SMILES 字串

O.Cl[Ru](Cl)Cl

InChI

1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3

InChI 密鑰

BIXNGBXQRRXPLM-UHFFFAOYSA-K

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相关类别

一般說明

可溶型

應用

它被用于制备纳米颗粒钌-氢氧化铝氧化物催化剂，使芳甲基醇有效脱氢生成相应的醛。该产物可催化由伯芳香胺和三烯丙基胺合成2-乙基-3-甲基喹啉。使用 RhCl3 在二氧化钛纳米管上沉积制备的钌水合氧化物，可用作分子氧选择性氧化醇的催化体系。

特點和優勢

Ruthenium(III) Chloride hydrate ReagentPlus® has been designed and tested keeping the requirements of research applications with low insoluble matters, specifications ensuring the material is suitable for high-performance applications and provides consistency in experimental and industrial processes.

法律資訊

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

訊號詞

Danger

危險聲明

H302,H314,H411

危險分類

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

分析证书(COA)

输入产品批号来搜索 分析证书(COA) 。批号可以在产品标签上"批“ （Lot或Batch）字后找到。

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TiO 2 nanotube-supported ruthenium (III) hydrated oxide: A highly active catalyst for selective oxidation of alcohols by oxygen.
Bavykin DV, et al.
J. Catal., 235(1), 10-17 (2005)
Meser M Ali et al.
Journal of nanomedicine & nanotechnology, 10(6), 35248/2157-35248/7439 (2020-01-30)
Dye-sensitized solar cells (DSSCs) have attracted enormous attention in the last couple of decades due to their relatively small size, low cost and minimal environmental impact. DSSCs convert solar energy to electrical energy with the aid of a sensitizing dye.
Synthesis of ruthenium complexes and their catalytic applications: A review
Hafeez J, et al.
Arabian Journal of Chemistry, 15, 104165-104165 (2022)
Ruthenium(III) Chloride as an Efficient Catalyst for the Selective Oxidation of Fatty Alcohols to Aldehydes
Nunheim F N, et al.
ChemistrySelect, 8, e202300346-e202300346 (2023)
Won-Hee Kim et al.
Organic letters, 8(12), 2543-2545 (2006-06-02)
An efficient oxidant-free oxidation for a wide range of alcohols was achieved by a recyclable ruthenium catalyst. The catalyst was prepared from readily available reagents by a one-pot synthesis through nanoparticle generation and gelation. [structure: see text]
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