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Merck
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文件

178756

Sigma-Aldrich

叠氮磷酸二苯酯

97%

别名:

DPPA, 二苯基磷酰叠氮化物

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About This Item

线性分子式:
(C6H5O)2P(O)N3
CAS号:
26386-88-9
分子量:
275.20
Beilstein:
2058967
EC號碼:
247-644-0
MDL號碼:
MFCD00001987
分類程式碼代碼:
12352302
PubChem物質ID:
24850766
NACRES:
NA.22

品質等級

200

化驗

97%

形狀

liquid

反應適用性

reaction type: click chemistry

折射率

n20/D 1.551 (lit.)

bp

157 °C/0.17 mmHg (lit.)

密度

1.277 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

[N-]=[N+]=NP(=O)(Oc1ccccc1)Oc2ccccc2

InChI

1S/C12H10N3O3P/c13-14-15-19(16,17-11-7-3-1-4-8-11)18-12-9-5-2-6-10-12/h1-10H

InChI 密鑰

SORGEQQSQGNZFI-UHFFFAOYSA-N

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相关类别

應用

氢氧叠氮催化有机叠氮化物粗制备

在改良Curtis重排反应中，用作合成连接氨基甲酸酯和尿素键的低聚糖合成试剂
四苯基钴卟啉催化的烯烃氮杂环化反应。
在制备大环内酰胺和醛糖还原酶抑制剂过程中，用作活化剂。

象形圖

Skull and crossbones
GHS06

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

233.6 °F - closed cup

閃點（°C）

112 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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The Journal of Organic Chemistry, 71, 6665-6665 (2006)
Tetrahedron Letters, 31, 6469-6469 (1990)
Qiaoya Li et al.
European journal of medical research, 22(1), 48-48 (2017-11-23)
This study aimed to investigate the therapeutic effects of 5-fluorouracil (5-FU)-loaded nanobubbles irradiated with low-intensity, low-frequency ultrasound in nude mice with hepatocellular carcinoma (HCC). A transplanted tumor model of HCC in nude mice was established in 40 mice, which were
Kenichi Tanaka et al.
Molecular bioSystems, 4(6), 512-514 (2008-05-22)
A Vaska-type complex carrying a ferrocene-appended diphosphine ligand was developed as a prototype of autonomous molecular machines that is able to undergo continuous scissoring motion in the presence of diphenylphosphoryl azide and aldehyde.
Charles S Zahedi et al.
Journal of periodontology, 74(7), 1071-1079 (2003-08-23)
Several bioabsorbable collagen membranes are either currently available or under investigation for use in guided tissue regeneration (GTR) procedures. The aim of this 12-month reentry study was to evaluate a diphenylphosphorylazide (DPPA)-cross-linked bovine type I collagen membrane in the healing
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