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Merck

O7805

Sigma-Aldrich

Oleylamin

technical grade, 70%

Synonym(e):

cis-1-Amino-9-octadecen, cis-1-Amino-9-octadecen

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35,30 €
100 G
49,90 €
500 G
163,00 €

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5 G
35,30 €
100 G
49,90 €
500 G
163,00 €

About This Item

Lineare Formel:
CH3(CH2)7CH=CH(CH2)7CH2NH2
CAS-Nummer:
Molekulargewicht:
267.49
Beilstein:
1723960
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12162002
PubChem Substanz-ID:
NACRES:
NA.23

35,30 €


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Qualität

technical grade

Qualitätsniveau

Dampfdruck

8 mmHg ( 135 °C)

Assay

70%

Zusammensetzung

primary amine, >98%

Brechungsindex

n20/D 1.4596 (lit.)

bp

348-350 °C (lit.)

mp (Schmelzpunkt)

18-26 °C (lit.)

Dichte

0.813 g/mL at 25 °C (lit.)

SMILES String

[H]\C(CCCCCCCC)=C(/[H])CCCCCCCCN

InChI

1S/C18H37N/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19/h9-10H,2-8,11-19H2,1H3/b10-9-

InChIKey

QGLWBTPVKHMVHM-KTKRTIGZSA-N

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Allgemeine Beschreibung

Oleylamin (OAm) ist ein langkettiges primäres Alkyamin, das bei erhöhten Temperaturen als Elektronenspender fungiert. OAM weist über die funktionalen NH2-Gruppen Affinität zu Metallen auf. FTIR-Spektren von OAm wurden beschrieben.[1] Oleylamin fungiert als starkes Reduktionsmittel sowie als Stabilisator bei der Synthese von Nanopartikeln.[2]

Anwendung

Wird verwendet in der chemischen Synthese und Kappung von Nanopartikeln[1], wie Fe3O4, Poly (2-Hydroxyethylmethacrylat)-Transplantat-Poly (ε-Caprolacton),[3] Titandioxid,[4] mesoporöser Kieselerde.[5]

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 - STOT SE 3

Zielorgane

Respiratory system

Lagerklassenschlüssel

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flammpunkt (°F)

309.2 °F - closed cup

Flammpunkt (°C)

154 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

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Besitzen Sie dieses Produkt bereits?

In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Oleylamine in nanoparticle synthesis.
Mourdikoudis S and Liz-Marzan LM
Chemistry of Materials, 25(9), 1465-1476 (2013)
Fe3O4 @ poly (2-hydroxyethyl methacrylate)-graft-poly (ε-caprolactone) magnetic nanoparticles with branched brush polymeric shell.
Yuan W, et al.
Polymer, 51(12), 2540-2547 (2010)
Monty Liong et al.
ACS nano, 2(5), 889-896 (2009-02-12)
Drug delivery, magnetic resonance and fluorescence imaging, magnetic manipulation, and cell targeting are simultaneously possible using a multifunctional mesoporous silica nanoparticle. Superparamagnetic iron oxide nanocrystals were encapsulated inside mesostructured silica spheres that were labeled with fluorescent dye molecules and coated
Oleylamine as both reducing agent and stabilizer in a facile synthesis of magnetite nanoparticles.
Xu Z, et al.
Chemistry of Materials, 21(9), 1778-1780 (2009)
Nadica D Abazović et al.
The journal of physical chemistry. B, 110(50), 25366-25370 (2006-12-15)
Nonaqueous reactions between titanium(IV) chloride and alcohols (benzyl alcohol or n-butanol) were used for the synthesis of anatase TiO2 particles, while rutile TiO2 particles were synthesized in aqueous media by acidic hydrolysis of titanium(IV) chloride. The X-ray diffraction measurements proved

Artikel

Solvothermal synthesis of nanoparticles: applications from nanocircuits and nano-optical circuits to nanomagnetics and biotech.

Prof. Randal Lee discusses iron oxide magnetic nanospheres and nanocubes design considerations for biosensing applications.

Magnetic nanoparticles have attracted tremendous attention due to their novel properties and their potential applications in magnetic recording, magnetic energy storage and biomedicine.

Fragen

1-4 von 4 Fragen  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 Antwort
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 Antwort
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Hilfreich?

  3. is it fine to store Oleylamine in plastic vials? Does it reacts with plastic or rubber cork present in the glass vials cap?

    1 Antwort
    1. This product is packaged in amber glass bottles and polypropylene screw caps with EPDM/PTFE liners. Compatibility testing with plastics and/or rubber corks has not been performed. Generally, plastic vials and rubber corks are chemically inert and often nonreactive with most chemicals. However, leaching or degradation cannot be ruled out. It is recommended that this material be stored in the original or similar containers to preserve the quality of the compound.

      Hilfreich?

  4. Is the O7805 Oleylamine technical grade 70% considered contaminated if the bottle arrived very cloudy?

    1 Antwort
    1. The material has a melting point between 18 °C and 26 °C, and it is normal for the product to become cloudy or precipitate in cold temperatures. The product is specified as a clear to hazy liquid, and gentle heating can be applied to restore its clarity

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