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Merck

256811

Sigma-Aldrich

Diisobutylaluminiumhydrid

reagent grade

Synonym(e):

DIBAH, DIBAL

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About This Item

Lineare Formel:
[(CH3)2CHCH2]2AlH
CAS-Nummer:
Molekulargewicht:
142.22
Beilstein:
4123663
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352001
PubChem Substanz-ID:
NACRES:
NA.22
Preise und Verfügbarkeit sind derzeit nicht verfügbar.

Qualität

reagent grade

Qualitätsniveau

Eignung der Reaktion

reagent type: reductant

bp

116-118 °C/1 mmHg (lit.)

Dichte

0.798 g/mL at 25 °C (lit.)

SMILES String

[H][Al](CC(C)C)CC(C)C

InChI

1S/2C4H9.Al.H/c2*1-4(2)3;;/h2*4H,1H2,2-3H3;;

InChIKey

AZWXAPCAJCYGIA-UHFFFAOYSA-N

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Allgemeine Beschreibung

Diisobutylaluminum hydride is commonly used as a reducing agent in organic synthesis.[1]

Anwendung

Diisobutylaluminum hydride can be used in the following protocols:
  • As a promotor of Tishchenko reaction of aldehydes.[2]
  • Conversion of benzylidene acetals of 1,2-and 1,3-glycols to the corresponding monobenzyl ethers of the glycols.[3]
  • To generate a novel chiral reducing agent based on (S)-proline for the asymmetric reduction of prochiral ketones.[4]

Verpackung

Packaged in Sure/Pac carbon steel cylinders with 1/4" NPTM chrome-plated bronze ball valve

Rechtliche Hinweise

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC

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Piktogramme

FlameCorrosion

Signalwort

Danger

Gefahreneinstufungen

Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B - Water-react 1

Zusätzliche Gefahrenhinweise

Lagerklassenschlüssel

4.2 - Pyrophoric and self-heating hazardous materials

WGK

nwg

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Analysenzertifikate (COA)

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Kunden haben sich ebenfalls angesehen

Tishchenko reactions of aldehydes promoted by diisobutylaluminum hydride and its application to the macrocyclic lactone formation.
Hon YS, et al.
Tetrahedron, 63(46), 11325-11340 (2007)
Asymmetric reduction of prochiral keto esters with a chiral reducing agent prepared from tin (II) chloride, chiral diamine, and diisobutylaluminum hydride.
Mukaiyama T, et al.
Chemistry Letters (Jpn), 14(6), 813-816 (1985)
A facile cleavage of benzylidene acetals with diisobutylaluminum hydride.
Takano S, et al.
Chemistry Letters (Jpn), 12(10), 1593-1596 (1983)
Daisuke Ando et al.
Journal of agricultural and food chemistry, 66(39), 10154-10162 (2018-09-13)
The metabolic fate of a new fungicide, mandestrobin, labeled with 14C at the phenoxy or benzyl ring was examined in wheat after a single spray application at 300 g/ha. Mandestrobin penetrated into foliage over time, with both radiolabels showing similar
Reaction of diisobutylaluminum hydride with selected organic compounds containing representative functional groups
Yoon N M
The Journal of Organic Chemistry, 50(14), 2443-2450 (1985)

Fragen

1-2 von 2 Fragen  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 Antwort
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Hilfreich?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 Antwort
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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