532878

Methyl 4-bromo-3-methylbenzoate

95%

• Lineární vzorec: BrC₆H₃(CH₃)CO₂CH₃
• Číslo CAS: 148547-19-7
• Molekulová hmotnost: 229.07
• NACRES: NA.22
• PubChem Substance ID: 24877922
• UNSPSC Code: 12352100
• MDL number: MFCD00673014
• Assay: 95%

Vlastnosti

• Quality Segment: 100
• assay: 95%
• mp: 38-44 °C (lit.)
• functional group: bromo, ester
• SMILES string: COC(=O)c1ccc(Br)c(C)c1
• InChI: 1S/C9H9BrO2/c1-6-5-7(9(11)12-2)3-4-8(6)10/h3-5H,1-2H3
• InChI key: GTZTYNPAPQKIIR-UHFFFAOYSA-N

Popis

General description

Methyl 4-bromo-3-methylbenzoate, an aromatic ester, undergoes Suzuki coupling with 2-chloroboronic acid to afford the corresponding biaryl.

Application

Methyl 4-bromo-3-methylbenzoate may be used in the preparation of:

• 4-bromo-3-vinylbenzoic acid
• 4-bromo-3-(methylphenyl)methanol
• methyl (E)-4-bromo-3-[(phenylmethoxyimino)methyl]benzoate

It may be used as a starting material in the total synthesis of (-)-martinellic acid.

Bezpečnostní informace

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Skladovací třída: 10 - Combustible liquids
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type ABEK (EN14387) respirator filter