528013

Dimethyl disulfide

≥99%

• Synonyma: DMDS, Methyl disulfide
• Lineární vzorec: CH₃SSCH₃
• Číslo CAS: 624-92-0
• Molekulová hmotnost: 94.20
• Beilstein/REAXYS Number: 1730824
• EC Number: 210-871-0
• MDL number: MFCD00008561
• UNSPSC Code: 12352200
• PubChem Substance ID: 24874662
• NACRES: NA.22

Vlastnosti

• vapor density: 3.24 (vs air)
• Quality Level: 100
• vapor pressure: 22 mmHg ( 20 °C)
• assay: ≥99%
• autoignition temp.: >572 °F
• expl. lim.: 16 %
• availability: available only in EU
• refractive index: n20/D 1.525 (lit.)
• bp: 109 °C (lit.)
• mp: −85 °C (lit.)
• density: 1.046 g/mL at 25 °C (lit.)
• functional group: disulfide
• SMILES string: CSSC
• InChI: 1S/C2H6S2/c1-3-4-2/h1-2H3
• InChI key: WQOXQRCZOLPYPM-UHFFFAOYSA-N

Popis

Application

Dimethyl disulfide can be used:

• For the sulfidation of WS₂ nanoparticles during the preparation of WS₂/SBA15 mesoporous silica composite.
• In the copper-catalyzed sulfenylation of 2,3-allenoic acids to afford 4-sulfenylated butenolides.
• To synthesize various aryl sulfides by nickel-catalyzed thiolation of aryl iodides.
• Along with triflic anhydride, as a promoter for glycosylation reaction.
• In the copper-catalyzed 1,2-hydroxysulfenylation of alkenes to synthesize 1,2-acetoxysulfides.
• In the synthesis of sulfur containing polycyclic aromatic hydrocarbons such as dibenzoannelated tetrathienoacene.

Legal Information

Product of Arkema

Bezpečnostní informace

• pictograms: GHS02,GHS06,GHS08,GHS09
• signalword: Danger
• hcodes: H225,H301 + H331,H317,H319,H336,H370,H410
• pcodes: P210 - P273 - P280 - P301 + P310 - P303 + P361 + P353 - P304 + P340 + P311
• Hazard Classifications: Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Sens. 1 - STOT SE 1 Inhalation - STOT SE 3
• target_organs: Central nervous system, Upper respiratory tract
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: 59.0 °F - closed cup
• flash_point_c: 15 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter