467448

Triethylsilane

97%

• Synonyma: NSC 93579, Triethylhydrosilane, Triethylsilicon hydride
• Lineární vzorec: (C₂H₅)₃SiH
• Číslo CAS: 617-86-7
• Molekulová hmotnost: 116.28
• Beilstein/REAXYS Number: 1098278
• EC Number: 210-535-3
• MDL number: MFCD00009018
• UNSPSC Code: 12352103
• PubChem Substance ID: 24870410
• NACRES: NA.22

Vlastnosti

• assay: 97%
• reaction suitability: reagent type: reductant
• refractive index: n20/D 1.412 (lit.)
• bp: 107-108 °C (lit.)
• density: 0.728 g/mL at 25 °C (lit.)
• SMILES string: CC[SiH](CC)CC
• InChI: 1S/C6H16Si/c1-4-7(5-2)6-3/h7H,4-6H2,1-3H3
• InChI key: AQRLNPVMDITEJU-UHFFFAOYSA-N

Popis

Application

Catalyst for:

• Synthesis of a spiro-oxindole blocker of Nav1.7 for the treatment of pain
• Redox initiated cationic polymerization
• Beckmann rearrangement of cyclododecanone oxime
• Regioselective reductive coupling of enones and allenes

Catalyst reactivation after catalyst polymerization of styrene

Studies involving the prediction of organosilicon flash points

Triethylsilane can be used as:

• A reducing agent in the regioselective reductive coupling of enones and allenes.
• A reagent in the redox initiated cationic polymerization.
• A reagent in catalytic transfer hydrogenation, reduction of alkyl halides and silylation of aromatic C-H bonds, etc.
• As a reagent for the generation of indium hydride (Cl2InH) applicable as a catalyst for the intramolecular cyclization of enynes.

Bezpečnostní informace

• pictograms: GHS02,GHS07
• signalword: Danger
• hcodes: H225,H315,H319,H335
• pcodes: P210 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 2
• flash_point_f: 21.2 °F
• flash_point_c: -6 °C
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter