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391638

Sigma-Aldrich

Dimethylphosphoramidous dichloride

97%

Synonyma:

(Dichlorophosphanyl)dimethylamine, (Dimethylamino)dichlorophosphine, Dichloro(dimethylamido)phosphorus, Dichloro(dimethylamino)phosphine, Dichloro-N,N-dimethylaminophosphine, N,N-Dimethylphosphoramidous dichloride

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About This Item

Lineární vzorec:
(CH3)2NPCl2
Číslo CAS:
683-85-2
Molekulová hmotnost:
145.96
MDL number:
MFCD00013613
UNSPSC Code:
12352100
PubChem Substance ID:
24864392
NACRES:
NA.22

assay

97%

form

liquid

refractive index

n20/D 1.505 (lit.)

bp

150 °C (lit.)

density

1.271 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CN(C)P(Cl)Cl

InChI

1S/C2H6Cl2NP/c1-5(2)6(3)4/h1-2H3

InChI key

XPWWDZRSNFSLRQ-UHFFFAOYSA-N

Související kategorie

General description

Dimethylphosphoramidous dichloride (dimethylaminodichlorophosphine) is a phosphorus chloride derivative. It exists in two stable isomers, a gauche-conformer with C1 symmetry and anti-conformer with Cs symmetry. Its synthesis has been reported. Molecular conformation has been investigated through correlation between the 35Cl NQR frequencies and charge on the chlorine atoms. Its vibrational spectra has been studied. Its reaction with SO2 has been investigated. It participates in the synthesis of [(dimethylamino)phosphoryl] bis(difluoromethylene)phosphonate.

Application

Dimethylphosphoramidous dichloride (N,N-dimethylamidodichlorophosphite) may be used in the synthesis of the following:
  • N,N-dimethylamidotetrachlorophosphorane
  • O-propylchloroformimino-N,N-dimethylamidochlorophosphate
  • 1,3-bisarylsulphonyl-1,3,2,4-diazadiphosphetidines

pictograms

FlameCorrosion
GHS02,GHS05

signalword

Danger

hcodes

H225,H314

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

supp_hazards

EUH014

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

-9.4 °F - closed cup

flash_point_c

-23 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Osvědčení o analýze (COA)

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Sigma-Aldrich

D71984

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Sigma-Aldrich

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Equilibrium conformation of dimethylaminodichlorophosphine molecule: the use of the results of quantum-chemical calculations and spectroscopic measurements in the analysis of gas-phase electron diffraction data.
Khaikin LS, et al.
Russian Chemical Bulletin, 50(9), 1550-1562 (2001)
G K Surya Prakash et al.
Proceedings of the National Academy of Sciences of the United States of America, 107(36), 15693-15698 (2010-08-21)
It is difficult to overestimate the importance of nucleoside triphosphates in cellular chemistry: They are the building blocks for DNA and RNA and important sources of energy. Modifications of biologically important organic molecules with fluorine are of great interest to
Reaction of 1, 1-dichloro-1-nitrosobutane with N, N-dimethylamidodichlorophosphite.
Sokolov VB, et al.
Bulletin of the Academy of Sciences of the USSR, Division of chemical science, 38(6), 1296-1298 (1989)
35Cl NQR spectra of phosphorus chlorides and their molecular conformations in crystals. Part 1. Phosphorus (III) chlorides RPCl2.
Kozlov ES, et al.
Journal of Molecular Structure, 550, 167-175 (2000)
Dimethylaminodimethylphosphine1.
Burg AB and Slota Jr PJ.
Journal of the American Chemical Society, 80(5), 1107-1109 (1958)
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