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Merck

211273

Sigma-Aldrich

Zinc chloride

ACS reagent, ≥97%

Sinónimos:

Dichlorozinc

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About This Item

Fórmula lineal:
ZnCl2
Número de CAS:
Peso molecular:
136.30
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21

grade

ACS reagent

Quality Level

vapor pressure

1 mmHg ( 428 °C)

assay

≥97%

form

crystalline powder
powder, crystals or chunks

reaction suitability

reagent type: catalyst
core: zinc

impurities

Oxychloride, passes test
≤0.005% insolubles

pH

5 (20 °C, 100 g/L)

mp

293 °C (lit.)

anion traces

nitrate (NO3-): ≤0.003%
sulfate (SO42-): ≤0.01%

cation traces

Ca: ≤0.06%
Fe: ≤0.001%
K: ≤0.02%
Mg: ≤0.01%
NH4+: ≤0.005%
Na: ≤0.05%
Pb: ≤0.005%

SMILES string

[Cl-].[Cl-].[Zn++]

InChI

1S/2ClH.Zn/h2*1H;/q;;+2/p-2

Inchi Key

JIAARYAFYJHUJI-UHFFFAOYSA-L

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General description

Zinc chloride in combination with 1-ethyl-3-methylimidazolium chloride comprises a molten salt, which is employed in the electrodeposition studies of zinc on various substrates (glassy carbon and nickel).

Application

Zinc chloride may be used as a catalyst for the Knoevenagel condensation of aromatic aldehydes with substituted acetonitriles to form carbonyl-methylene products under solvent-free conditions. The activation of sugar cane bagasse with zinc chloride forms activated carbons for use as supercapacitor electrodes.
ZnCl2 may be employed as a catalyst in the preparation of carbonyl-methylene condensation products and poly(propylene fumarate).

Legal Information

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Microstructure and electrochemical double-layer capacitance of carbon electrodes prepared by zinc chloride activation of sugar cane bagasse.
Rufford TE, et al.
Journal of Power Sources, 195(3), 912-918 (2010)
Albert K Shung et al.
Journal of biomaterials science. Polymer edition, 13(1), 95-108 (2002-05-11)
Diethyl fumarate and propylene glycol were reacted in the presence of a zinc chloride catalyst to synthesize poly(propylene fumarate) (PPF) over a period of 12 hours. The kinetics of the transesterification polymerization at 130 degrees C, 150 degrees C, and
Electrodeposition of zinc from a Lewis acidic zinc chloride-1-ethyl-3-methylimidazolium chloride molten salt.
Lin Y-F and Sun I.
Electrochimica Acta, 44(16), 2771-2777 (1999)
Zinc chloride as a new catalyst for Knoevenagel condensation.
Shanthan RP and Venkataratnam RV.
Tetrahedron Letters, 32(41), 5821-5822 (1991)
Kaushik Nath et al.
Environmental science and pollution research international, 20(6), 4030-4045 (2012-12-06)
Utilization of agrowaste materials for the production of activated carbon, as an excellent adsorbent with large surface area, is well established industrially, for dephenolation of wastewater. In the present work, dried pods of Prosopis cineraria-a novel and low-cost agrowaste material-were

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