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79408

Sigma-Aldrich

Phosphazene base P1-t-Bu

≥97.0% (GC)

Sinónimos:

tert-Butylimino-tris(dimethylamino)phosphorane, N′-tert-Butyl-N,N,N′,N′,N″,N″-hexamethylphosphorimidic triamide

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About This Item

Fórmula empírica (notación de Hill):
C10H27N4P
Número de CAS:
81675-81-2
Peso molecular:
234.32
Beilstein/REAXYS Number:
4178783
MDL number:
MFCD00145111
UNSPSC Code:
12352001
PubChem Substance ID:
57652790
NACRES:
NA.22

Quality Level

100

assay

≥97.0% (GC)

form

liquid

SMILES string

CN(C)P(N(C)C)(N(C)C)=NC(C)(C)C

InChI

1S/C10H27N4P/c1-10(2,3)11-15(12(4)5,13(6)7)14(8)9/h1-9H3

InChI key

YRNOSHBJMBLOSL-UHFFFAOYSA-N

Application

Phosphazene Bases: a Family of Extremely Strong, Non-Ionic, Non-Charged Nitrogen–Bases

Other Notes

Sterically hindered, neutral nitrogen base with similar basicity as BEMP (Cat. No. 20025); Base for dehydrating carbamate anions to isocyanates with POCl3 or P4O10

pictograms

Health hazardCorrosion
GHS08,GHS05

signalword

Danger

Hazard Classifications

Carc. 1B - Eye Dam. 1 - Muta. 1B - Skin Corr. 1B

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificados de análisis (COA)

Lot/Batch Number
BCCH5640
BCBW5899
BCBT9517
BCBM1851V
BCBH2522V

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T.E. Waldman et al.
Journal of the Chemical Society. Chemical Communications, 957-957 (1994)
R. Schwesinger et al
Angewandte Chemie (International Edition in English), 105, 1420-1420 (1994)
Lan-Fang Hu et al.
Molecules (Basel, Switzerland), 25(2) (2020-01-16)
The copolymerization of biorenewable succinic anhydride (SA) with propylene oxide (PO) is a promising way to synthesize biodegradable aliphatic polyesters. However, the catalytic systems for this reaction still deserve to be explored because the catalytic activity of the reported catalysts

Artículos

Phosphazene Bases

Phosphazene base reagents are available as monomeric (P1 and BEMP), dimeric (P2), and tetrameric (P4) bases with different side chains to control their sterical hindrance.

Phosphazene Bases

Phosphazene base reagents are available as monomeric (P1 and BEMP), dimeric (P2), and tetrameric (P4) bases with different side chains to control their sterical hindrance.

Phosphazene Bases

Phosphazene base reagents are available as monomeric (P1 and BEMP), dimeric (P2), and tetrameric (P4) bases with different side chains to control their sterical hindrance.

Phosphazene Bases

Phosphazene base reagents are available as monomeric (P1 and BEMP), dimeric (P2), and tetrameric (P4) bases with different side chains to control their sterical hindrance.

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