222380

Allylpalladium(II) chloride dimer

98%

• Sinónimos: Bis((η3-allyl)(chloro)palladium), Di-ο-allyldi-μ-chlorodipalladium, [PdCl(C₃H₅)]₂
• Fórmula empírica (notación de Hill): C₆H₁₀Cl₂Pd₂
• Número de CAS: 12012-95-2
• Peso molecular: 365.89
• Beilstein: 4124623
• Número CE: 234-579-8
• Número MDL: MFCD00044874
• Código UNSPSC: 12161600
• ID de la sustancia en PubChem: 24853328
• NACRES: NA.22

Propiedades

• Nivel de calidad: 200
• Ensayo: 98%
• Formulario: solid
• idoneidad de la reacción: core: palladium; reaction type: Cross Couplings; reagent type: catalyst; reaction type: C-H Activation
• características de los productos alternativos más sostenibles: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• categoría alternativa más sostenible: , Aligned
• temp. de almacenamiento: 2-8°C
• cadena SMILES: Cl[Pd]CC=C.Cl[Pd]CC=C
• InChI: 1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q;;;;2*+1/p-2
• Clave InChI: TWKVUTXHANJYGH-UHFFFAOYSA-L

Descripción

Descripción general

Allylpalladium(II) chloride dimer is employed as catalyst in Heck reaction. It also participates as catalyst in the tandem nucleophilic allylation-alkoxyallylation reaction of the alkynylaldehydes with allyl chloride and allyltributylstannane.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Aplicación

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Allylpalladium(II) chloride dimer has been employed for the following studies:

• Synthesis of cationic palladium cataysts, used in the microwave-assisted Heck arylation.
• Synthesis of N-heterocyclic carbene-palladium-η³-allyl chloride complexes, which are efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides.
• Synthesis of 1,4-diallyl-1,2-dihydroisoquinolines.
• As catalyst for greener Buchwald-Hartwig coupling in TPGS-750-M.

On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors

Información de seguridad

• Pictogramas: GHS07
• Palabra de señalización: Warning
• Frases de peligro: H315
• Consejos de prudencia: P264 - P280 - P302 + P352 - P332 + P313 - P362 + P364
• Clasificaciones de peligro: Skin Irrit. 2
• Código de clase de almacenamiento: 11 - Combustible Solids
• Clase de riesgo para el agua (WGK): WGK 3
• Equipo de protección personal: dust mask type N95 (US), Eyeshields, Faceshields, Gloves