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159530

Sigma-Aldrich

2-Bromo-4′-methylacetophenone

90%

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About This Item

Fórmula lineal:
CH3C6H4COCH2Br
Número de CAS:
619-41-0
Peso molecular:
213.07
EC Number:
210-595-0
MDL number:
MFCD00000203
UNSPSC Code:
12352100
PubChem Substance ID:
24849819
NACRES:
NA.22

assay

90%

bp

105 °C/0.1 mmHg (lit.)

mp

45-49 °C (lit.)

functional group

bromo

storage temp.

2-8°C

SMILES string

Cc1ccc(cc1)C(=O)CBr

InChI

1S/C9H9BrO/c1-7-2-4-8(5-3-7)9(11)6-10/h2-5H,6H2,1H3

InChI key

KRVGXFREOJHJAX-UHFFFAOYSA-N

General description

2-Bromo-4′-methylacetophenone is an α-bromoketone.

Application

2-Bromo-4′-methylacetophenone was used in the general fluorous thiol quenching method. It was also used in the preparation of hydroxyquinolinone and N-derivatized carboxamides.

Pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Miroslav Soural et al.
Journal of combinatorial chemistry, 9(5), 793-796 (2007-08-07)
A highly efficient solid-phase synthesis of 2-substituted-3-hydroxy-4(1H)-quinolinone-7-carboxamides was developed using anthranilates and bromoketones as the key synthons. Primary amines immobilized to an acid-cleavable BAL linker were acylated with 1-methyl-2-aminoterephtalate. After cleavage of the methyl ester, bromoketones were used to form
Use of fluorous silica gel to separate fluorous thiol quenching derivatives in solution-phase parallel synthesis
Zhang W, et al.
Tetrahedron, 58(20), 3871-3875 (2002)
Hana Elshaflu et al.
Frontiers in chemistry, 6, 247-247 (2018-07-19)
The novel approach in the treatment of complex multifactorial diseases, such as neurodegenerative disorders and cancer, requires a development of efficient multi-targeting oriented drugs. Since oxidative stress significantly contributes to the pathogenesis of cancer and neurodegenerative disorders, potential drug candidates

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