637998
Vinylboronic anhydride pyridine complex
95%
Sinonimo/i:
2,4,6-Trivinylcyclotriboroxane pyridine complex, Trivinyl-boroxin pyridine complex, Trivinylcyclotriboroxane pyridine complex
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1 G
CHF 79.40
5 G
CHF 340.00
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Cambia visualizzazione
1 G
CHF 79.40
5 G
CHF 340.00
About This Item
Formula empirica (notazione di Hill):
C6H9B3O3 · C5H5N
Numero CAS:
Peso molecolare:
240.67
Numero MDL:
Codice UNSPSC:
12352103
ID PubChem:
NACRES:
NA.22
Prodotti consigliati
Saggio
95%
Stato
solid
Temperatura di conservazione
−20°C
Stringa SMILE
c1ccncc1.C=Cb2ob(C=C)ob(C=C)o2
InChI
1S/C6H9B3O3.C5H5N/c1-4-7-10-8(5-2)12-9(6-3)11-7;1-2-4-6-5-3-1/h4-6H,1-3H2;1-5H
YLHJACXHRQQNQR-UHFFFAOYSA-N
Categorie correlate
Applicazioni
Reagent used for
Reagent used for Preparation of
- Suzuki-Miyaura cross-coupling[1][2]
- Stereoselective synthesis via Palladium-catalyzed carboamination[3]
- Alkyl-connected 2-amino-6-vinylpurine (AVP) crosslinking agent to cytosine base in RNA[4]
- Kaiser oxime resin-derived palladacycle as a recoverable polymeric precatalyst in Suzuki-Miyaura cross-coupling reactions in aqueous media[5]
- Kinetic resolution of phosphoryl and sulfonyl esters of binaphthol derivatives via Pd-catalyzed alcoholysis of their vinyl ethers[6]
- Stereoselective isomerization of N-allyl aziridines into Z-enamines by using rhodium hydride catalysis[7]
- Kinetic resolution of axially chiral biaryl derivatives via palladium/chiral diamine ligand-catalyzed alcoholysis[8]
- Transition metal-catalyzed alkenylation of aziridines, cycloaddition and thermal rearrangement reactions[9]
- Intramolecular Heck reaction strategy for synthesis of functionalized tetrahydroanthracenes[10]
Reagent used for Preparation of
Avvertenze
Warning
Indicazioni di pericolo
Consigli di prudenza
Classi di pericolo
Eye Irrit. 2
Codice della classe di stoccaggio
11 - Combustible Solids
Classe di pericolosità dell'acqua (WGK)
WGK 3
Punto d’infiammabilità (°F)
176.0 °F - closed cup
Punto d’infiammabilità (°C)
80 °C - closed cup
Dispositivi di protezione individuale
dust mask type N95 (US), Eyeshields, Gloves
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I clienti hanno visto anche
Kinetic resolution of axially chiral 2,2'-dihydroxy-1,1'-biaryls by palladium-catalyzed alcoholysis.
Hiroshi Aoyama et al.
Journal of the American Chemical Society, 127(30), 10474-10475 (2005-07-28)
Palladium-diamine complexes catalyzed kinetic resolution of axially chiral 2,2'-dihydroxy-1,1'-biaryls by alcoholysis of vinyl ethers. The reaction proceeded with high selectivity for various kinds of biaryls. This process is applicable to not only binaphthols but also biphenols, which have been considered
Shadi Dalili et al.
Organic letters, 7(6), 1161-1164 (2005-03-12)
[reaction: see text] Straightforward methods for palladium-catalyzed alkenylation of aziridines with alkenyl halides and copper-catalyzed alkenylation of aziridines with alkenyl boronic acids have been developed. This methodology offers attractive alternatives to the known methods requiring activated alkenyl halides and acetylenes.
Kaiser oxime resin-derived palladacycle: A recoverable polymeric precatalyst in Suzuki-Miyaura reactions in aqueous media
Alacid, E.; Najera, C.
Journal of Organometallic Chemistry, 694, 1658-1665 (2009)
Heinrich Rueeger et al.
Bioorganic & medicinal chemistry letters, 21(7), 1942-1947 (2011-03-11)
This Letter describes the de novo design of non-peptidic hydroxyethylamine (HEA) inhibitors of BACE-1 by elimination of P-gp contributing amide attachments. The predicted binding mode of the novel cyclic sulfone HEA core template was confirmed in a X-ray co-crystal structure.
Yosuke Taniguchi et al.
Bioorganic & medicinal chemistry, 18(8), 2894-2901 (2010-03-30)
We have previously reported that the 2-amino-6-vinylpurine (AVP) nucleoside exhibits a highly efficient and selective crosslinking reaction toward cytosine and displayed an improved antisense inhibition in cultured cells. In this study, we further investigated the alkyl-connected AVP nucleoside analogs for
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