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Sigma-Aldrich

Pyromellitic dianhydride

97%

Sinonimo/i:

Benzene-1,2,4,5-tetracarboxylic dianhydride, PMDA

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About This Item

Formula empirica (notazione di Hill):
C10H2O6
Numero CAS:
Peso molecolare:
218.12
Beilstein:
213583
Numero CE:
Numero MDL:
Codice UNSPSC:
12162002
ID PubChem:
NACRES:
NA.23

Livello qualitativo

Saggio

97%

Stato

powder

P. ebollizione

397-400 °C (lit.)

Punto di fusione

283-286 °C (lit.)

Stringa SMILE

O=C1OC(=O)c2cc3C(=O)OC(=O)c3cc12

InChI

1S/C10H2O6/c11-7-3-1-4-6(10(14)16-8(4)12)2-5(3)9(13)15-7/h1-2H
ANSXAPJVJOKRDJ-UHFFFAOYSA-N

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Descrizione generale

Pyromellitic dianhydride is a dianhydride class of monomers commonly used in the preparation of polyimides polymers which are used in aerospace, electronics, and automotive industries because of their excellent thermal stability, high mechanical strength, and inherent flame resistance. It is also used in the synthesis of thermoplastic polymers such as polyesters and polyethers, as well as plasticizers and epoxy resins. Additionally, PMDA serves as a curing agent for epoxy resins. Epoxy resins are widely used in adhesives, coatings, composites, and electrical insulation materials.

Pyromellitic dianhydride (PMDA) is an acidic anhydride that can be used as a repair agent and as a chain extender in the formation of polyethylene terephthalate (PET) based chain extensions. It is mainly used in the production of thermoplastics and other coating applications.

Applicazioni

PMDA can be used as:
  • A monomer to synthesize aromatic polyimides with excellent thermo-mechanical and chemical properties. These polymers find the applications in automotive and electronic industries.
  • A capping agent in the development of siloxane-based hybrid materials for potential usage in organic electronics.
  • A monomer in the preparation and modification of thin film composite membranes, which are used in water purification, gas separation, and biomedical devices.
  • A monomer in the synthesis of pyromellitic diimide-based copolymers as stable cathode active materials for lithium and sodium-ion batteries.

Pittogrammi

Health hazardCorrosion

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Eye Dam. 1 - Resp. Sens. 1 - Skin Sens. 1

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

716.0 °F - closed cup

Punto d’infiammabilità (°C)

380 °C - closed cup

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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Jun-Xia Yu et al.
Bioresource technology, 110, 160-166 (2012-02-22)
Magnetic pyromellitic dianhydride (PMDA) modified sugarcane bagasse (SCB) was prepared by a situ co-precipitation method. Results showed that the magnetic modified SCB could be recycled easily by an applied magnetic field. Adsorption capacities of the magnetic sorbent for cationic dyes:
Reparation of recycled acrylonitrile-butadiene-styrene by pyromellitic dianhydride: reparation performance evaluation and property analysis
Li Y, et al.
Polymer, 124(3), 41-47 (2017)
Wei Hu et al.
Technometrics : a journal of statistics for the physical, chemical, and engineering sciences, 62(2), 196-205 (2020-06-12)
We propose a novel linear discriminant analysis (LDA) approach for the classification of high-dimensional matrix-valued data that commonly arises from imaging studies. Motivated by the equivalence of the conventional LDA and the ordinary least squares, we consider an efficient nuclear
Anastasia Anceschi et al.
Molecules (Basel, Switzerland), 25(13) (2020-07-08)
Carbon-based materials with different morphologies have special properties suitable for application in adsorption, catalysis, energy storage, and so on. Carbon spheres and carbon monoliths are also nanostructured materials showing promising results. However, the preparation of these materials often require the
Jiemin Wang et al.
ACS nano, 13(7), 7860-7870 (2019-06-14)
Conventional three-dimensional (3D) thermal conductors or heat sinks are normally bulky solids with high density, which is cumbersome and not portable to satisfy current demands for soft and flexible electronic devices. To address this issue, here, a lightweight, superelastic yet

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