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151440

Sigma-Aldrich

Methyl chlorooxoacetate

96%

Sinonimo/i:

Monomethyl oxalyl chloride, Chloroglyoxylic acid methyl ester, Methyl (chloroformyl)formate, Methyl 2-chloro-2-oxoacetate, Methyl chloroglyoxalate, Methyl oxalyl chloride

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5 G
CHF 92.50
10 G
CHF 102.00
50 G
CHF 332.00

CHF 92.50


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Cambia visualizzazione
5 G
CHF 92.50
10 G
CHF 102.00
50 G
CHF 332.00

About This Item

Formula condensata:
ClCOCOOCH3
Numero CAS:
Peso molecolare:
122.51
Beilstein:
1071541
Numero CE:
Numero MDL:
Codice UNSPSC:
12352101
ID PubChem:
NACRES:
NA.22

CHF 92.50


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Livello qualitativo

Saggio

96%

Impiego in reazioni chimiche

reagent type: oxidant

Indice di rifrazione

n20/D 1.419 (lit.)

P. ebollizione

118-120 °C (lit.)

Densità

1.332 g/mL at 25 °C (lit.)

Gruppo funzionale

acyl chloride
ester

Stringa SMILE

COC(=O)C(Cl)=O

InChI

1S/C3H3ClO3/c1-7-3(6)2(4)5/h1H3
ZXUQEPZWVQIOJE-UHFFFAOYSA-N

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Applicazioni

Reactant involved in:
  • Regioselective synthesis of fused coumarins
  • Cyclization to form substituted isoxazoles and heterocycles
  • Intramolecular Wittig reactions
  • Silyl enol ether acylation
  • Iron-mediated cleavage of C-C bonds

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

114.8 °F - closed cup

Punto d’infiammabilità (°C)

46 °C - closed cup

Dispositivi di protezione individuale

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Certificati d'analisi (COA)

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Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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