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72240

Sigma-Aldrich

Aluminium-Nickel-Legierung

purum, 50% Al basis, 50% Ni basis

Synonym(e):

Nickel-Aluminium-Legierung, Raney®-Nickel-Legierung

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100 G
CHF 70.80
500 G
CHF 119.00

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100 G
CHF 70.80
500 G
CHF 119.00

About This Item

CAS-Nummer:
MDL-Nummer:
UNSPSC-Code:
12161600
PubChem Substanz-ID:
NACRES:
NA.22

CHF 70.80


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Qualitätsniveau

Qualität

purum

Form

powder

Zusammensetzung

Al, 50%
Ni, 50%

Eignung der Reaktion

core: nickel
reagent type: catalyst

SMILES String

[Al].[Ni]

InChI

1S/Al.Ni

InChIKey

NPXOKRUENSOPAO-UHFFFAOYSA-N

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Anwendung

Aluminum-nickel alloy can be used:
  • For the reduction of nitriles, nitro compounds and oximes to primary amines.[1]
  • For the conversion of carbonyl compounds to hydrocarbons.[2]
  • As a reducing agent to convert Ar-X derivatives to Ar-H compounds.[1]
  • For the synthesis of Raney nickel catalyst to be used as an alkylating agent.[3][4]
  • To synthesize non-pyrophoric Ni catalyst by alkali leaching.[5]
  • For the synthesis of alloyed skeletal Ni catalysts.[6]

Rechtliche Hinweise

Raney is a registered trademark of W.R. Grace & Co.-Conn.

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Preisangaben

Signalwort

Danger

Gefahreneinstufungen

Carc. 2 - Flam. Sol. 1 - Skin Sens. 1 - Water-react 2

Lagerklassenschlüssel

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Analysenzertifikate (COA)

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In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Highly selective hydrogenation of C?C double bond in unsaturated carbonyl compounds over NiC catalyst.
Mahata N, et al.
Chemical Engineering Journal, 188(4), 155-159 (2012)
An environmentally benign and catalytically efficient non-pyrophoric Ni catalyst for aqueous-phase reforming of ethylene glycol.
Zhu LJ, et al.
Green Chemistry, 10(12), 1323-1330 (2008)
Reinvestigating Raney nickel mediated selective alkylation of amines with alcohols via hydrogen autotransfer methodology.
Mehta A, et al.
Applied Catalysis A: General, 478(4), 241-251 (2014)
Nickel-aluminum alloy as a reducing agent.
Keefer LK and Lunn G
Chemical Reviews, 89(3), 459-502 (1989)
Steam reforming of ethanol over skeletal Ni-based catalysts: A temperature programmed desorption and kinetic study
Zhang C, et al.
AIChE Journal, 60(2), 635-644 (2014)

Artikel

An article concerning self-propagating reactions induced by mechanical alloying, presented by Sigma-Aldrich.com.

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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