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Merck

24897

Supelco

Chlorid-Ionophor I

Selectophore

Synonym(e):

meso-Tetraphenylporphyrin Mangan(III)-chlorid Komplex

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About This Item

Empirische Formel (Hill-System):
C44H28ClMnN4
CAS-Nummer:
Molekulargewicht:
703.11
Beilstein:
5699425
MDL-Nummer:
UNSPSC-Code:
26111700
PubChem Substanz-ID:
NACRES:
NB.61

Qualität

for ion-selective electrodes

Qualitätsniveau

Produktlinie

Selectophore

SMILES String

Cl[Mn]1n2c3ccc2c(-c4ccccc4)c5ccc(n5)c(-c6ccccc6)c7ccc(c(-c8ccccc8)c9ccc(n9)c3-c%10ccccc%10)n17

InChI

1S/C44H28N4.ClH.Mn/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36;;/h1-28H;1H;/q-2;;+3/p-1/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-;;

InChIKey

MIUMWNDEIWVIEG-YKKPBKTHSA-M

Allgemeine Beschreibung

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Anwendung

Selected application examples
Tetraphenylporphyrin manganese (III) chloride complex generally finds application in determining histidine in aqueous solutions by resonance light scattering technique.

Verpackung

Bottomless glass bottle. Contents are inside inserted fused cone.

Sonstige Hinweise

Chlorid-Ionophor in einer Celluloseacetat-Membran-Elektrode

Rechtliche Hinweise

Selectophore is a trademark of Merck KGaA, Darmstadt, Germany

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Preisangaben

Piktogramme

Exclamation mark

Signalwort

Warning

Gefahreneinstufungen

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Zielorgane

Respiratory system

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Gloves


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High-field and -frequency electron paramagnetic resonance (HFEPR) spectroscopy has been used to study three complexes of high spin Manganese(III), 3d4, S = 2. The complexes studied were tetraphenylporphyrinatomanganese(III) chloride (MnTPPCI), phthalocyanatomanganese(III) chloride (MnPcCl), and (8,12-diethyl-2,3,7,13,17,18-hexamethylcorrolato)manganese(III) (MnCor). We demonstrate the ability

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