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Merck

195758

Sigma-Aldrich

Tetramethylammoniumbromid

98%

Synonym(e):

TMAB

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CHF 32.90
500 G
CHF 118.00

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Voraussichtliches Versanddatum31. Mai 2025


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100 G
CHF 32.90
500 G
CHF 118.00

About This Item

Lineare Formel:
(CH3)4N(Br)
CAS-Nummer:
Molekulargewicht:
154.05
Beilstein:
3620955
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.21

CHF 32.90


Voraussichtliches Versanddatum31. Mai 2025


Bulk-Bestellung anfordern

Qualität

for analytical purposes

Qualitätsniveau

Assay

98%

Form

solid

mp (Schmelzpunkt)

>300 °C (lit.)

Funktionelle Gruppe

amine

SMILES String

[Br-].C[N+](C)(C)C

InChI

1S/C4H12N.BrH/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1

InChIKey

DDFYFBUWEBINLX-UHFFFAOYSA-M

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Allgemeine Beschreibung

Tetrabutylammonium bromide is a quaternary ammonium compound that is widely used as a phase transfer catalyst.[1] Absolute viscosities of its aqueous solutions have been measured at various temperatures (20,25 and 30°C).[2] Various physical properties (activity coefficient up to saturation, conductance, density and solubility in water) of TMABr have been evaluated.[3]
Tetramethylammonium bromide (TMABr) is a quaternary ammonium salt that is widely used as a phase transfer catalyst.[1] Absolute viscosities of its aqueous solutions have been measured at various temperatures (20,25 and 30°C).[2] Various physical properties (activity coefficient up to saturation, conductance, density and solubility in water) of TMABr have been evaluated.[3] Its impact on the first order rate constant values for the base hydrolysis of the following Fe(II) chelates has been investigated:[4]




  • bis(naphthylidene alanate) (nali)
  • bis(naphthylidene phenylalanate) (nphali)
  • bis(naphthylidene aspartate) (nasi)
  • (naphthylidene histidinate) (nhi)
  • bis(naphthylidenearginate) (nari)

Anwendung

Tetrabutylammonium bromide may be used in the molten state in the following processes:
  • Synthesis of (2S)-5-(3-phenyl-2-phthalimidylpropanoylamino)isophthalic acid.[5]
  • Synthesis of alkyl-substituted pyrroles in the absence of catalyst and organic solvent.[6]
  • Synthesis of dithioacetals from acetals by transthioacetalisation in a solvent free environment.[7]
  • Synthesis of polyamides (PAs) by the polymerization of terephthalic acid and diisocyanates.[8]
  • Catalyze the addition of thiols to conjugated alkenes.[9]
  • Dehydrochlorination of poly(vinyl chloride). [10]
Tetramethylammonium bromide may be used as a template in the synthesis of small colloidal zeolite Y nanocrystals.[11]

Piktogramme

Skull and crossbones

Signalwort

Danger

H-Sätze

Gefahreneinstufungen

Acute Tox. 2 Oral

Lagerklassenschlüssel

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Die Dokumentenbibliothek aufrufen

Viscosity of aqueous solutions. III. Tetramethylammonium bromide and the role of the tetraalkylammonium ions.
Nightingale Jr ER.
The Journal of Physical Chemistry, 66(5), 894-897 (1962)
Controlling size and yield of zeolite Y nanocrystals using tetramethylammonium bromide.
Holmberg BA, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 59(1), 13-28 (2003)
Dehydrochlorination of poly (vinyl chloride) by aqueous sodium hydroxide solution under two-phase conditions.
Kise H.
Journal of Polymer Science, 20(11), 3189-3197 (1982)
Some physical properties of aqueous solutions of tetramethylammonium bromide and tetramethylammonium iodide
Levien BJ.
Australian Journal of Chemistry, 18(8), 1161-1170 (1965)
Kinetic study of the base-catalyzed hydrolysis of novel high-spin hydrophobic Fe(II)-azomethine amino acid chelates: Salt and structure effects on the reactivity
Russian Journal of General Chemistry, 85, 168-172 (2015)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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