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Merck

16966

Supelco

Aldicarb-(N-methyl-13C,d3-carbamoyl-13C)

PESTANAL®, analytical standard

Synonym(e):

(1E)-2-Methyl-2-(methylthio)-O-[(methyl-13C-d3-amino)-carbonyl-13C]oxim-propanal

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About This Item

Empirische Formel (Hill-System):
13C2C5D3H11N2O2S
CAS-Nummer:
Molekulargewicht:
195.27
MDL-Nummer:
UNSPSC-Code:
77101502
PubChem Substanz-ID:
NACRES:
NA.24

Qualität

analytical standard

Qualitätsniveau

Beschreibung

Isotopic Enrichment ≥98%

Produktlinie

PESTANAL®

Assay

≥98.5% (HPLC)

Haltbarkeit

limited shelf life, expiry date on the label

Anwendung(en)

agriculture
environmental

Format

neat

Massenverschiebung

M+5

Lagertemp.

−20°C
−20°C

SMILES String

[2H][13C]([2H])([2H])N[13C](=O)O\N=C\C(C)(C)SC

InChI

1S/C7H14N2O2S/c1-7(2,12-4)5-9-11-6(10)8-3/h5H,1-4H3,(H,8,10)/b9-5+/i3+1D3,6+1

InChIKey

QGLZXHRNAYXIBU-FONWFMSDSA-N

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Verwandte Kategorien

Allgemeine Beschreibung

Aldicarb-(N-methyl-13C,d3, carbamoyl-13C) is an isotope-labeled analog of aldicarb, a carbamate pesticide, used as an insecticide and nematicide for the control of pests in agriculture.

Anwendung

Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The main advantage of using the IDMS technique is because isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analog, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.

Hinweis zur Analyse

Isotopic Enrichment ≥98%

Rechtliche Hinweise

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Piktogramme

Skull and crossbonesEnvironment

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 1 Oral - Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 1

Lagerklassenschlüssel

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


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Die Dokumentenbibliothek aufrufen

Chronic exposure to aldicarb-contaminated groundwater and human immune function
Fiore CM, et al.
Environmental Research, 41(2), 633-645 (1986)
Aldicarb poisoning
Ragouc-Sengler C, et al.
Human & Experimental Toxicology, 19(12), 657-662 (2000)
Determination of aldicarb, aldicarb oxime, and aldicarb nitrile in water by gas chromatography/mass spectrometry.
Trehy ML, et al.
Analytical Chemistry, 56(8), 1281-1285 (1984)

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