In situ chemical oxidation with persulfate anion (S2O82*) is a viable technique for remediation of groundwater contaminants such as trichloroethylene (TCE). An accelerated reaction using S2O82* to destroy TCE can be achieved via chemical activation with ferrous ion to generate
Journal of the American Chemical Society, 132(16), 5837-5844 (2010-04-03)
By palladium catalysis, the C-H bond functionalization of O-phenylcarbamates with simple arenes has been achieved using sodium persulfate (Na(2)S(2)O(8)), an inexpensive, easy-to-handle, and environmentally friendly oxidant. This oxidative cross-coupling involves two aromatic C-H bonds undergoing concomitant oxidation to furnish a
Journal of hazardous materials, 196, 153-159 (2011-10-05)
The potential for 13 naturally occurring minerals to mediate the decomposition of persulfate and generate a range of reactive oxygen species was investigated to provide fundamental information on activation mechanisms when persulfate is used for in situ chemical oxidation (ISCO).
Journal of hazardous materials, 244-245, 370-379 (2012-12-29)
The photocatalytic degradation of sixteen substituted phenylurea herbicides (PUHs) in pure water has been studied using zinc oxide (ZnO) and titanium dioxide (TiO(2)) as photocatalyst under artificial light irradiation. Photocatalytic experiments showed that the addition of these chalcogenide oxides in
Using ultraviolet photolytic persulfate activation to produce two sulfate radicals (SO(4)(-)) exhibits a potential for destroying organic contaminants in wastewater treatment applications. This study investigated both the feasibility of using a UV/SPS (sodium persulfate) process to treat phenol in aqueous
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