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Merck

P29006

Sigma-Aldrich

Phenylphosphonsäure

98%

Synonym(e):

Benzene phosphonic acid

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100 G
CHF 77.00
500 G
CHF 256.00

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5 G
CHF 57.80
100 G
CHF 77.00
500 G
CHF 256.00

About This Item

Lineare Formel:
C6H5P(O)(OH)2
CAS-Nummer:
Molekulargewicht:
158.09
Beilstein:
2245168
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352300
PubChem Substanz-ID:
NACRES:
NA.23

CHF 57.80


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Qualitätsniveau

Assay

98%

Form

crystals

mp (Schmelzpunkt)

162-164 °C (lit.)

SMILES String

OP(O)(=O)c1ccccc1

InChI

1S/C6H7O3P/c7-10(8,9)6-4-2-1-3-5-6/h1-5H,(H2,7,8,9)

InChIKey

QLZHNIAADXEJJP-UHFFFAOYSA-N

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Anwendung

Additiv zur Verwendung mit Noyori-Katalysator zur Oxidation von Sulfiden zu Sulfonen.

Noyori-Oxidation (Natrium-Wolframat-Dihydrat, Wasserstoffperoxid, Methyltri-n-octylammoniumhydrogensulfat, Phosphorsäure)
Selbstorganisierte Monoschichten (SAM) aus Phenylphosphonsäure können verwendet werden, um die Schnittstelle zwischen organischen Halbleitern und transparenten leitfähigen Oxiden zu erzeugen.[1] Die Säure kann verwendet werden, um Titanteilchen zu funktionalisieren.[2] Additiv zur Verwendung mit Noyoriι-Katalysator zur grüneren Oxidation von Sulfiden zu Sulfonen.

Piktogramme

CorrosionExclamation mark

Signalwort

Danger

H-Sätze

Gefahreneinstufungen

Acute Tox. 4 Oral - Skin Corr. 1B

Lagerklassenschlüssel

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Analysenzertifikate (COA)

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In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Christel Gervais et al.
Magnetic resonance in chemistry : MRC, 42(5), 445-452 (2004-04-20)
1H, 13C, 17O and 31P NMR parameters, including chemical shift tensors and quadrupolar parameters for 17O, were calculated for phenylphosphonic acid, C6H5PO(OH)2, under periodic boundary conditions. The results are in very good agreement with experimental data and permit the unambiguous
Jannie P Wijnen et al.
PloS one, 9(7), e102256-e102256 (2014-07-19)
To assess the ability of a polarization transfer (PT) magnetic resonance spectroscopy (MRS) technique to improve the detection of the individual phospholipid metabolites phosphocholine (PC), phosphoethanolamine (PE), glycerophosphocholine (GPC), and glycerophosphoethanolamine (GPE) in vivo in breast tumor xenografts. The adiabatic
K Hendrich et al.
Journal of magnetic resonance. Series B, 105(3), 225-232 (1994-11-01)
Spatial localization with the spectroscopic imaging technique is normally implemented with the Fourier-transform approach, yielding rectangular voxels, with potentially significant cross-voxel contamination. Multidimensional Fourier-series window (FSW) is an alternate approach that generates single voxels of predetermined shape, with minimal out-of-voxel
Zhaohui Cui et al.
Langmuir : the ACS journal of surfaces and colloids, 26(1), 179-182 (2009-08-04)
The in situ crystallization technique has been utilized to fabricate zirconium phenylphosphonate (ZrPP) films with their hexagonal crystallite perpendicular to the copper substrate. The micro/nano roughness surface structure, as well as the intrinsic hydrophobic characteristic of the surface functional groups
M W Fryer et al.
Journal of muscle research and cell motility, 18(2), 161-167 (1997-04-01)
The rate, magnitude and pharmacology of inorganic phosphate (Pi) transport into the sarcoplasmic reticulum were estimated in single, mechanically skinned skeletal muscle fibres of the rat. This was done, indirectly, by using a technique that measured the total Ca2+ content

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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