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M31104

Sigma-Aldrich

α-Methylbenzylamin

99%

Synonym(e):

(±)-α-Methylbenzylamin, (±)-1-Phenyl-ethylamin

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About This Item

Lineare Formel:
C6H5CH(CH3)NH2
CAS-Nummer:
618-36-0
Molekulargewicht:
121.18
Beilstein:
636127
EG-Nummer:
210-545-8
MDL-Nummer:
MFCD00008069
UNSPSC-Code:
12352100
PubChem Substanz-ID:
24896793
NACRES:
NA.22

Assay

99%

Form

liquid

Brechungsindex

n20/D 1.526 (lit.)

bp

185 °C/756 mmHg (lit.)

Dichte

0.94 g/mL at 25 °C (lit.)

SMILES String

CC(N)c1ccccc1

InChI

1S/C8H11N/c1-7(9)8-5-3-2-4-6-8/h2-7H,9H2,1H3

InChIKey

RQEUFEKYXDPUSK-UHFFFAOYSA-N

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Allgemeine Beschreibung

α-Methylbenzylamine is a nitrogen source that is widely used as a representative substrate to study the chemo-enzymatic kinetic resolution of primary amines.

Anwendung

α-Methylbenzylamine can be used as a reactant for the synthesis of dihydro-5H-dibenz[c,e]azepinium salts by reacting with racemic biphenol derivatives.
It is used in the synthesis of o-fluorobenzylamines.

Piktogramme

CorrosionExclamation mark
GHS05,GHS07

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Lagerklassenschlüssel

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flammpunkt (°F)

158.0 °F - closed cup

Flammpunkt (°C)

70 °C - closed cup

Persönliche Schutzausrüstung

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Analysenzertifikate (COA)

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Die Dokumentenbibliothek aufrufen

Chemoenzymatic dynamic kinetic resolution of primary amines.
Paetzold, Jens and Backvall, Jan E
Journal of the American Chemical Society, 127(50), 17620-17621 (2005)
Nora Weber et al.
Microbial cell factories, 16(1), 3-3 (2017-01-05)
Whole-cell biocatalysis based on metabolically active baker's yeast with engineered transamination activity can be used to generate molecules carrying a chiral amine moiety. A prerequisite is though to express efficient ω-transaminases and to reach sufficient intracellular precursor levels. Herein, the
Boyeong Kang et al.
Scientific reports, 7(1), 4786-4786 (2017-07-08)
The energy flow during natural photosynthesis is controlled by maintaining the spatial arrangement of pigments, employing helices as scaffolds. In this study, we have developed porphyrin-peptoid (pigment-helix) conjugates (PPCs) that can modulate the donor-acceptor energy transfer efficiency with exceptional precision
Kinetic resolution of ??methylbenzylamine with o?transaminase screened from soil microorganisms: Application of a biphasic system to overcome product inhibition.
Shin, Jong-Shik and Kim, Byung-Gee
Biotechnology and Bioengineering, 55(2), 348-358 (1997)
Jan Dines Knudsen et al.
Microbial cell factories, 15, 37-37 (2016-02-18)
Saccharomyces cerevisiae can be engineered to perform a multitude of different chemical reactions that are not programmed in its original genetic code. It has a large potential to function as whole-cell biocatalyst for one-pot multistep synthesis of various organic molecules
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