H10401

Hexamethylenimin

99%

• Synonym(e): Hexahydro-1H-azepin, Homopiperidin
• Empirische Formel (Hill-System): C₆H₁₃N
• CAS-Nummer: 111-49-9
• Molekulargewicht: 99.17
• Beilstein: 1084
• EG-Nummer: 203-875-9
• MDL-Nummer: MFCD00006934
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24895424
• NACRES: NA.22

Eigenschaften

• Dampfdruck: 7.4 mmHg ( 21.1 °C)
• Assay: 99%
• Form: liquid
• Brechungsindex: n20/D 1.466 (lit.)
• bp: 138 °C/749 mmHg (lit.)
• Dichte: 0.88 g/mL at 25 °C (lit.)
• SMILES String: C1CCCNCC1
• InChI: 1S/C6H13N/c1-2-4-6-7-5-3-1/h7H,1-6H2
• InChIKey: ZSIQJIWKELUFRJ-UHFFFAOYSA-N

Beschreibung

Anwendung

Hexamethyleneimine (HMI) can be used in the preparation of:

• zeolitic catalysts such as MCM-22 and MCM-49
• SAPO-35, a molecular sieve
• various microporous aluminosilicates and titanosilicates
• organic-inorganic hybrid pervoskite

It can also been used in the total synthesis of various natural products and bioactive molecules such as (−)-balanol, indole estrogens, derivatives of daunorubicin and (+)-cetiedil.

Sicherheitshinweise

• Piktogramme: GHS02,GHS06,GHS05
• Signalwort: Danger
• H-Sätze: H225,H300,H314,H331,H335
• P-Sätze: P210 - P233 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 2 Oral - Acute Tox. 3 Inhalation - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1C - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): 64.4 °F - closed cup
• Flammpunkt (°C): 18 °C - closed cup
• Persönliche Schutzausrüstung: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter