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775053

Sigma-Aldrich

Lithium-bis-(trimethylsilyl)-amid -Lösung

greener alternative

0.5 M in 2-methyltetrahydrofuran

Synonym(e):

Hexamethyldisilazan Lithiumsalz

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100 ML
CHF 94.00
4 X 25 ML
CHF 102.00
800 ML
CHF 603.00

CHF 94.00


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100 ML
CHF 94.00
4 X 25 ML
CHF 102.00
800 ML
CHF 603.00

About This Item

Lineare Formel:
[(CH3)3Si]2NLi
CAS-Nummer:
Molekulargewicht:
167.33
Beilstein:
3567910
MDL-Nummer:
UNSPSC-Code:
12352111
PubChem Substanz-ID:
NACRES:
NA.22

CHF 94.00


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Form

liquid

Qualitätsniveau

Grünere Alternativprodukt-Eigenschaften

Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Inherently Safer Chemistry for Accident Prevention
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Konzentration

0.5 M in 2-methyltetrahydrofuran

Dichte

0.857 g/mL at 25 °C

Grünere Alternativprodukt-Kategorie

SMILES String

[Li]N([Si](C)(C)C)[Si](C)(C)C

InChI

1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1

InChIKey

YNESATAKKCNGOF-UHFFFAOYSA-N

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Allgemeine Beschreibung

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 0.5 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention. Click here for more information.

Anwendung

Significantly accelerated the polymerization of phenylacetylene in conjunction with rhodium(I) catalysis.[1]
Strong organic base in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Verpackung

The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Rechtliche Hinweise

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Self-heat. 1 - Skin Corr. 1B

Zusätzliche Gefahrenhinweise

Lagerklassenschlüssel

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 2

Flammpunkt (°F)

8.6 °F

Flammpunkt (°C)

-13 °C


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Die Dokumentenbibliothek aufrufen

Macromolecules, 39, 5347-5347 (2006)
Nur Hazlin Hazrin-Chong et al.
Journal of microbiological methods, 90(2), 96-99 (2012-05-09)
The use of hexamethyldisilazane (HMDS) as a drying agent was investigated in the specimen preparation for scanning electron microscopy (SEM) imaging of bacterial surface colonization on sub-bituminous coal. The ability of microbes to biofragment, ferment and generate methane from coal
Elsa Vennat et al.
Dental materials : official publication of the Academy of Dental Materials, 25(6), 729-735 (2009-01-29)
The objectives of this study were to assess demineralized dentin porosity and quantify the different porous features distribution within the material using mercury intrusion porosimetry (MIP) technique. We compared hexamethyldisilazane (HMDS) drying and lyophilization (LYO) (freeze-drying) in sample preparation. Fifty-six
Nan Li et al.
Lab on a chip, 8(12), 2105-2112 (2008-11-22)
High-density live cell array serves as a valuable tool for the development of high-throughput immunophenotyping systems and cell-based biosensors. In this paper, we have, for the first time, demonstrated a simple fabrication process to form the hexamethyldisilazane (HMDS) and poly(ethylene
Xiaoguang Li et al.
Chemical communications (Cambridge, England), 47(38), 10761-10763 (2011-08-30)
A silica microsphere suspension and a silica sol are employed in a two-step dipping process for the preparation of a superhydrophobic surface. It's not only a facile way to achieve the lotus effect, but can also create a multi-functional surface

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