661058

Methoxy(cyclooctadien)rhodium(I)-dimer

• Synonym(e): [Rh(OMe)(1,5-cod)]₂
• Empirische Formel (Hill-System): C₁₈H₃₀O₂Rh₂
• CAS-Nummer: 12148-72-0
• Molekulargewicht: 484.24
• MDL-Nummer: MFCD08457639
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 24884497
• NACRES: NA.22

Eigenschaften

• Form: solid
• Qualitätsniveau: 100
• Eignung der Reaktion: core: rhodium; reagent type: catalyst
• mp (Schmelzpunkt): 192-225 °C
• Lagertemp.: −20°C
• SMILES String: CO[Rh].CO[Rh].C1CC=CCCC=C1.C2CC=CCCC=C2
• InChI: 1S/2C8H12.2CH3O.2Rh/c2*1-2-4-6-8-7-5-3-1;2*1-2;;/h2*1-2,7-8H,3-6H2;2*1H3;;/q;;2*-1;2*+1/b2*2-1-,8-7-;;;;
• InChIKey: BDQMDBOKWREKIT-MIXQCLKLSA-N

Beschreibung

Anwendung

Efficient and Selective Catalysts for Asymmetric Synthesis

Rhodium catalyst employed in the cyclization of cyano-substituted unsaturated esters in the presence of aryl 9-BBN leading to 5- and 6-membered β-enamino esters.

Precursor for organorhodium(I) species, catalyst for cascade1,4-addition-aldol reaction, 1,4-addition of alcohols, and hydroformylation

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable