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Methylindol-5-carboxylat
99%
Synonym(e):
Indole-5-carboxylic acid, methyl ester
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About This Item
Empirische Formel (Hill-System):
C10H9NO2
CAS-Nummer:
Molekulargewicht:
175.18
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.22
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Qualitätsniveau
Assay
99%
mp (Schmelzpunkt)
126-128 °C (lit.)
Funktionelle Gruppe
ester
SMILES String
COC(=O)c1ccc2[nH]ccc2c1
InChI
1S/C10H9NO2/c1-13-10(12)8-2-3-9-7(6-8)4-5-11-9/h2-6,11H,1H3
InChIKey
DRYBMFJLYYEOBZ-UHFFFAOYSA-N
Verwandte Kategorien
Allgemeine Beschreibung
Methyl indole-5-carboxylate (Methyl 1H-indole-5-carboxylate), a substituted 1H-indole, can be prepared by the esterification of indole-5-carboxylic acid. Its efficacy as a substrate for indigoid generation has been assessed.
Anwendung
Methyl indole-5-carboxylate may be used as a reactant in the following processes:
- biosynthesis of inhibitors of protein kinases
- metal-free Friedel-Crafts alkylation
- preparation of diphenylsulfonium ylides from Martin′s sulfurane
- cross dehydrogenative coupling reactions
- synthesis of indirubin derivatives
- preparation of aminoindolylacetates
Methyl indole-5-carboxylate may be used in the preparation of:
- methyl indoline-5-carboxylate
- 1H-indole-5-carbohydrazide
- dimethyl 1H-indole-3,5-dicarboxylate
Signalwort
Warning
H-Sätze
Gefahreneinstufungen
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Zielorgane
Respiratory system
Lagerklassenschlüssel
11 - Combustible Solids
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
Persönliche Schutzausrüstung
dust mask type N95 (US), Eyeshields, Gloves
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A direct ylide transfer to carbonyl derivatives and heteroaromatic compounds.
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This report describes the synthesis, and in vitro and in vivo antimalarial evaluations of certain ester-modified neocryptolepine (5-methyl-5H-indolo[2,3-b]quinoline) derivatives. The modifications were carried out by introducing ester groups at the C2 and/or C9 position on the neocryptolepine core and the
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A novel cross dehydrogenative coupling (CDC) reaction of N,N-dimethylanilines with methyl ketones by cooperative copper and aminocatalysis has been developed, which leads to the formation of β-arylamino ketones in 42-73% yields. Moreover, the copper-catalyzed alkylation of free (NH) indoles with
Wang, T. C.; et al.
Chinese Chemical Letters = Zhongguo Hua Xue Kuai Bao, 21, 1407-1407 (2010)
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