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3-Decin-1-ol
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About This Item
Lineare Formel:
CH3(CH2)5C≡CCH2CH2OH
CAS-Nummer:
Molekulargewicht:
154.25
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.22
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Assay
97%
Form
liquid
Brechungsindex
n20/D 1.459 (lit.)
bp
130-131 °C/22 mmHg (lit.)
Dichte
0.877 g/mL at 25 °C (lit.)
Funktionelle Gruppe
hydroxyl
SMILES String
CCCCCCC#CCCO
InChI
1S/C10H18O/c1-2-3-4-5-6-7-8-9-10-11/h11H,2-6,9-10H2,1H3
InChIKey
YGEQBZUDPQQIFI-UHFFFAOYSA-N
Allgemeine Beschreibung
3-Decyn-1-ol is primary homo-propargylic alcohol derivative. It has been reported to be formed during the isomerization of 2-decyn-1-ol in the presence of sodium salt of 1,3-diaminopropane. Its toxicity has been evaluated on the green alga, Pseudokirchneriella subcapitata in terms of EC50 (median effective concentration) and NOEC (no observed effect level) values. It undergoes semi hydrogenation in the presence of Lindlar catalyst to form cis-3-decen-1-ol.
Anwendung
3-Decyn-1-ol may be used in the following studies:
- As a starting material in the synthesis of 3′-deoxyribolactones.
- As a starting material in the synthesis of (Z)-3-decen-1-ol by hydrogenation over P-2 nickel.
- As a reagent in the synthesis of methyl 9-decynoate.
Signalwort
Warning
H-Sätze
Gefahreneinstufungen
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Zielorgane
Respiratory system
Lagerklassenschlüssel
10 - Combustible liquids
WGK
WGK 3
Flammpunkt (°F)
224.6 °F - closed cup
Flammpunkt (°C)
107 °C - closed cup
Persönliche Schutzausrüstung
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Synthesis of 3'-Deoxyribolactones using a Hydrolysis-Induced Lactonization Cascade Reaction of Epoxy Cyanohydrins.
Vugts DJ, et al.
European Journal of Organic Chemistry, 2008(8), 1336-1339 (2008)
Miriam F Cooperband et al.
Journal of chemical ecology, 38(1), 52-62 (2012-01-17)
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The rearrangement of isomeric linear decyn-1-ols by reaction with the sodium salt of 1, 3-diaminopropane.
Macaulay SR.
Canadian Journal of Chemistry, 58(23), 2567-2572 (1980)
Seiji Itoh et al.
Bioscience, biotechnology, and biochemistry, 66(7), 1591-1596 (2002-09-13)
Both the (17R)- and (17S)-isomers of volicitin, which is contained in the oral secretion of the beet armyworm and induces corn seedlings to emit a blend of volatile compounds to attract the natural enemy of the herbivore, were synthesized via
Chung Yuan Chen et al.
Journal of environmental monitoring : JEM, 14(1), 181-186 (2011-11-23)
The present study evaluates the toxicity of 34 propargylic alcohols, including primary, primary homo-, secondary, and tertiary alcohols, based on their effects on phytoplankton. A closed-system algal toxicity test was applied because the closed-system technique presents more realistic concentration-response relationships
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