405701

Allyl-P,P-diethylphosphonacetat

97%

• Synonym(e): Allyl-diethoxyphosphonoacetat
• Lineare Formel: (C₂H₅O)₂P(O)CH₂COOCH₂CH=CH₂
• CAS-Nummer: 113187-28-3
• Molekulargewicht: 236.20
• Beilstein: 1788582
• MDL-Nummer: MFCD00191710
• UNSPSC-Code: 12352108
• PubChem Substanz-ID: 24865325
• NACRES: NA.22

Eigenschaften

• Assay: 97%
• Form: liquid
• Eignung der Reaktion: reaction type: C-C Bond Formation
• Brechungsindex: n20/D 1.445 (lit.)
• bp: 157-158 °C/10 mmHg (lit.)
• Dichte: 1.12 g/mL at 25 °C (lit.)
• SMILES String: CCOP(=O)(CC(=O)OCC=C)OCC
• InChI: 1S/C9H17O5P/c1-4-7-12-9(10)8-15(11,13-5-2)14-6-3/h4H,1,5-8H2,2-3H3
• InChIKey: USZLAMOPIWNLPH-UHFFFAOYSA-N

Beschreibung

Anwendung

Reactant for:

• Horner-Wadsworth-Emmons reaction
• Preparation of phosphonate-functionalized cyclopentenones via regioselective Pauson-Khand processes
• Preparation of salicylihalamide analog saliphenylhalamide as potential vacuolar ATPase inhibitors and anticancer agents
• Solid-phase synthesis of olefin-containing peptides via Horner-Emmons reaction as inhibitors of HTLV-1 protease
• Synthesis of fluorescent poly(aromatic amide) dendrimers

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H319
• P-Sätze: P264 - P280 - P305 + P351 + P338 - P337 + P313
• Gefahreneinstufungen: Eye Irrit. 2
• Lagerklassenschlüssel: 10 - Combustible liquids
• WGK: WGK 3
• Flammpunkt (°F): 230.0 °F - closed cup
• Flammpunkt (°C): 110 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type ABEK (EN14387) respirator filter