389196

(3-Benzyloxypropyl)triphenylphosphoniumbromid

98%

• Lineare Formel: C₆H₅CH₂O(CH₂)₃P(C₆H₅)₃Br
• CAS-Nummer: 54314-85-1
• Molekulargewicht: 491.40
• MDL-Nummer: MFCD00191781
• UNSPSC-Code: 12352112
• PubChem Substanz-ID: 24864267
• NACRES: NA.22

Eigenschaften

• Assay: 98%
• Eignung der Reaktion: reaction type: C-C Bond Formation
• mp (Schmelzpunkt): 153-154 °C (lit.)
• SMILES String: [Br-].C(COCc1ccccc1)C[P+](c2ccccc2)(c3ccccc3)c4ccccc4
• InChI: 1S/C28H28OP.BrH/c1-5-14-25(15-6-1)24-29-22-13-23-30(26-16-7-2-8-17-26,27-18-9-3-10-19-27)28-20-11-4-12-21-28;/h1-12,14-21H,13,22-24H2;1H/q+1;/p-1
• InChIKey: DWYCJWXMZGVGJV-UHFFFAOYSA-M

Beschreibung

Anwendung

Reactant for preparation of:

• Spirocyclohexadienones via Pd-catalyzed intramolecular ipso-Friedel-Crafts allylic alkylation
• Inhibitors of heat shock protein (Hsp90) as antitumor agents
• Carpanone-like molecules via an oxidative coupling/Diels-Alder cycloaddition sequence

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves