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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
Wichtige Dokumente
377155
Chlor-bis(cycloocten)iridium(I)-dimer
97%
Synonym(e):
Di-μ-chlortetrakis-(cycloocten)-diiridium
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About This Item
Empfohlene Produkte
Assay
97%
Form
powder
Eignung der Reaktion
core: iridium
reagent type: catalyst
mp (Schmelzpunkt)
160-165 °C (dec.) (lit.)
SMILES String
Cl[Ir].Cl[Ir].[CH]1[CH]CCCCCC1.[CH]2[CH]CCCCCC2.[CH]3[CH]CCCCCC3.[CH]4[CH]CCCCCC4
InChI
1S/4C8H14.2ClH.2Ir/c4*1-2-4-6-8-7-5-3-1;;;;/h4*1-2H,3-8H2;2*1H;;/q;;;;;;2*+1/p-2/b4*2-1-;;;;
InChIKey
WBRREXQCZAFSKS-XFCUKONHSA-L
Verwandte Kategorien
Anwendung
- Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand
- Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions
- Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions
- Alkylation reactions
- Guerbet reaction
- Allylic amination reactions in a DNA-diene-iridium(I) hybrid system
- Asymmetric hydroamination reactions
- Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand.[1]
- Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions.[2]
- Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions.[3]
- Alkylation reactions.[4]
- Guerbet reaction.[5]
- Allylic amination reactions using a DNA-diene-iridium(I) hybrid system.[6]
- Asymmetric hydroamination reactions.[7]
Signalwort
Warning
H-Sätze
Gefahreneinstufungen
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Zielorgane
Respiratory system
Lagerklassenschlüssel
11 - Combustible Solids
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
Persönliche Schutzausrüstung
dust mask type N95 (US), Eyeshields, Gloves
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Artikel
Arylboronic acids and esters, vital tools in chemical transformations, find extensive use, particularly in the Suzuki-Miyaura cross-coupling reaction.
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How is shipping temperature determined? And how is it related to the product storage temperature?
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How can I determine the shelf life / expiration / retest date of this product?
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdfHelpful?
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