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Sigma-Aldrich

Phenyl-2-pyridylketoxim

98%

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About This Item

Empirische Formel (Hill-System):
C12H10N2O
CAS-Nummer:
1826-28-4
Molekulargewicht:
198.22
EG-Nummer:
217-374-8
MDL-Nummer:
MFCD00006310
UNSPSC-Code:
12352100
PubChem Substanz-ID:
24858215
NACRES:
NA.22

Assay

98%

Form

powder

mp (Schmelzpunkt)

154-156 °C (lit.)

SMILES String

O\N=C(/c1ccccc1)c2ccccn2

InChI

1S/C12H10N2O/c15-14-12(10-6-2-1-3-7-10)11-8-4-5-9-13-11/h1-9,15H/b14-12+

InChIKey

RSJDEVMJZLLAHS-WYMLVPIESA-N

Allgemeine Beschreibung

The complexation reaction of phenyl 2-pyridyl ketoxime with some transition and heavy metal ions Co2+, Ni2+, Zn2+, Pb2+, Fe2+, Fe3+, Cr3+ and La2+ has been studied potentiometrically. The reactions of phenyl(2-pyridyl)ketone oxime, with nickel(II) sulfate hexahydrate, in the absence of an external base, have been investigated.

Anwendung

Phenyl 2-pyridyl ketoxime was used in preparation of inverse-9-metallacrown-3, trinuclear clusters.

Qualität

May exhibit syn and anti forms

Piktogramme

Skull and crossbonesCorrosion
GHS06,GHS05

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

Zielorgane

Respiratory system

Lagerklassenschlüssel

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Analysenzertifikate (COA)

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Constantina Papatriantafyllopoulou et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 70(4), 718-728 (2007-10-10)
The reactions of phenyl(2-pyridyl)ketone oxime (py)C(ph)NOH, with nickel(II) sulfate hexahydrate under reflux, in the absence of an external base, have been investigated. The reaction of NiSO4 x 6H2O with two equivalents of (py)C(ph)NOH in H2O/MeOH leads to the dinuclear complex
Ardeshir Shokrollahi et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 71(2), 655-662 (2008-03-11)
The complexation reaction between some oximes including methyl-2-pyridylketone oxime (MPKO), phenyl-2-pyridylketone oxime (PPKO) and diacetyl monooxime (DMO) with some transition and heavy metal ions Co2+, Ni2+, Zn2+, Pb2+, Fe2+, Fe3+, Cr3+ and La3+ has been studied potentiometrically in aqueous solution
Tereza Afrati et al.
Dalton transactions (Cambridge, England : 2003), 39(3), 765-775 (2010-01-13)
Interaction of phenyl 2-pyridyl ketoxime (PhPyCNO)/X(-)"blends" (X(-) = OH(-), Cl(-), ClO(4)(-), 2,4-D) (2,4-DH = 2,4-dichlorophenoxyacetic acid) with copper perchlorate has yielded trinuclear clusters that have been characterized as inverse-9-metallacrown-3, accommodating one or two anions. The structure of the complex [Cu(3)(PhPyCNO)(3)(mu(3)-OH)(2,4-D)(2)]

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