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131377

Sigma-Aldrich

1,10-Phenanthrolin

≥99%

Synonym(e):

o-phenanthroline

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About This Item

Empirische Formel (Hill-System):
C12H8N2
CAS-Nummer:
66-71-7
Molekulargewicht:
180.21
EG-Nummer:
200-629-2
MDL-Nummer:
MFCD00011678
UNSPSC-Code:
12352100
eCl@ss:
39210124
PubChem Substanz-ID:
24848008
NACRES:
NA.22

Qualitätsniveau

200

Assay

≥99%

Form

powder

mp (Schmelzpunkt)

114-117 °C (lit.)

SMILES String

c1cnc2c(c1)ccc3cccnc23

InChI

1S/C12H8N2/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1/h1-8H

InChIKey

DGEZNRSVGBDHLK-UHFFFAOYSA-N

Angaben zum Gen

human ... FNTA(2339)

Verwandte Kategorien

Anwendung

1,10-Phenanthroline can be used as:
  • A cathode buffer layer to improve the efficiency of organic solar cells.
  • A conventional chelator to study its efficacy in Fenton′s reaction-luminol chemiluminescence system.
  • A ligand in mild, copper (II)-catalyzed cross-coupling of organoboronic acids and sulfinate salts, leading to aryl- and alkenylsulfones.
  • A versatile ligand employed in the spectrophotometric determination of metals and photocatalytic reduction of carbon dioxide.
  • A building block for metallomacrocycles.

Piktogramme

Skull and crossbonesEnvironment
GHS06,GHS09

Signalwort

Danger

H-Sätze

H301,H410

Gefahreneinstufungen

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Lagerklassenschlüssel

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Analysenzertifikate (COA)

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Mitsuhiro Wada et al.
Luminescence : the journal of biological and chemical luminescence, 29(7), 955-958 (2014-01-10)
In vitro screening of a Fe(2+) -chelating effect using a Fenton's reaction-luminol chemiluminescence (CL) system is described. The luminescence between the reactive oxygen species generated by the Fenton's reaction and luminol was decreased on capturing Fe(2+) using a chelator. The
Catalysis by Metal Complexes, 14, 217-217 (1993)
Neville S Ng et al.
Dalton transactions (Cambridge, England : 2003), 42(9), 3196-3209 (2012-12-13)
Copper(II) (1(Cu)-21(Cu)) and previously established experimental anticancer platinum(II) metallointercalator complexes (1(Pt)-16(Pt)) have been prepared and investigated for their antimicrobial properties. These complexes are of the general structure [M(I(L))(A(L))](2+) where I(L) represents functionalised 1,10-phenanthrolines (1(IL)-10(IL)), and A(L) represents 1,2-diaminoethane, 1S,2S- or
Aswan Sci. Technol. Bull., 13, 3-3 (1992)
Luiza Notini et al.
Environmental science & technology, 53(15), 8883-8891 (2019-07-10)
Surface defects have been shown to facilitate electron transfer between Fe(II) and goethite (α-FeOOH) in abiotic systems. It is unclear, however, whether defects also facilitate microbial goethite reduction in anoxic environments where electron transfer between cells and Fe(III) minerals is
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