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301868

Sigma-Aldrich

4,7-Phenanthrolin

98%

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About This Item

Empirische Formel (Hill-System):
C12H8N2
CAS-Nummer:
230-07-9
Molekulargewicht:
180.21
MDL-Nummer:
MFCD00004987
UNSPSC-Code:
12352100
PubChem Substanz-ID:
24858214
NACRES:
NA.22

Assay

98%

mp (Schmelzpunkt)

172-174 °C (lit.)

SMILES String

c1cnc2ccc3ncccc3c2c1

InChI

1S/C12H8N2/c1-3-9-10-4-2-8-14-12(10)6-5-11(9)13-7-1/h1-8H

InChIKey

DATYUTWESAKQQM-UHFFFAOYSA-N

Verwandte Kategorien

Allgemeine Beschreibung

4,7-Phenanthroline reacts with ruthenium carbonyl to yield cyclometalated derivatives.

Anwendung

4,7-Phenanthroline was used in preparation of:
  • cyclic tetranuclear half-sandwich ruthenium(II) complexes
  • positively charged homochiral cyclic trinuclear metallacalix[3]arene species

Piktogramme

CorrosionExclamation mark
GHS05,GHS07

Signalwort

Danger

H-Sätze

H302,H318

Gefahreneinstufungen

Acute Tox. 4 Oral - Eye Dam. 1

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves, type N95 (US)

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Sigma-Aldrich

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Journal of the American Chemical Society, 130(33), 11013-11022 (2008-07-26)
Variously substituted coordinating rigid rods have been synthesized which incorporate a central 4,7-phenanthroline nucleus attached to two 2-pyridyl groups via its 3 and 8 positions, so as to yield bis-bidentate chelates, the two-coordinating axes of the chelates being parallel to
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