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Merck

295086

Sigma-Aldrich

trans-2-Buten

≥99%

Synonym(e):

β-trans-Butylene, (2E)-2-Butene, (E)-2-Butene, 2-trans-Butene, 2-trans-Butylene, E-Butene, trans-1,2-Dimethylethylene, trans-2-Butylene, trans-Butene

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About This Item

Lineare Formel:
CH3CH=CHCH3
CAS-Nummer:
Molekulargewicht:
56.11
Beilstein:
1718756
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12142100
PubChem Substanz-ID:
NACRES:
NA.22
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Dampfdichte

2 (vs air)

Qualitätsniveau

Dampfdruck

2575 mmHg ( 37.7 °C)

Assay

≥99%

Selbstzündungstemp.

615 °F

Expl.-Gr.

9.7 %

bp

1 °C (lit.)

mp (Schmelzpunkt)

−105 °C (lit.)

SMILES String

CC=CC

InChI

1S/C4H8/c1-3-4-2/h3-4H,1-2H3/b4-3+

InChIKey

IAQRGUVFOMOMEM-ONEGZZNKSA-N

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Anwendung

trans-2-Butene can be used as a monomer unit to produce high molecular weight polyolefins with well-defined microstructures by nickle-catalyzed polymerization reaction. It is also used as a reactant in the isomerization reaction to produce the corresponding isomer using acid-activated catalysts.[1][2]

Verpackung

Supplied in a Sure/Pac cylinder and has a brass needle valve with a male 1/4" NPTF outlet thread installed. Before using the cylinder, ensure that the valve is closed, then remove the galvanized steel hex cap that seals the outlet valve.

Compatible with the following:

Rechtliche Hinweise

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC

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Piktogramme

FlameGas cylinder

Signalwort

Danger

H-Sätze

P-Sätze

Gefahreneinstufungen

Flam. Gas 1 - Press. Gas Liquefied gas

Lagerklassenschlüssel

2A - Gases

WGK

WGK 3

Flammpunkt (°F)

-4.0 °F - closed cup

Flammpunkt (°C)

-20 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves


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Analysenzertifikate (COA)

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In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Isomerization of cis-2-butene and trans-2-butene catalyzed by acid-and ion-exchanged smectite-type clays
Moronta A, et al.
Applied Clay Science, 29(2), 117-123 (2005)
Ni (II)-catalyzed polymerization of trans-2-butene
Leatherman MD and Brookhart M
Macromolecules, 34(9), 2748-2750 (2001)
J T Groves et al.
Progress in clinical and biological research, 274, 509-524 (1988-01-01)
A cytochrome P-450 LM2 reconstituted system mediated expoxidations of small terminal alkenes to the corresponding alkyloxiranes. This oxidation was accompanied by a stereoselective proton exchange of the E proton. Propene was oxidized in D2O to trans-3-deuterio-2-methyloxirane, and E-1-deuteriopropene was epoxidized
Duangkamol Gleeson
Journal of computer-aided molecular design, 22(8), 579-585 (2008-03-18)
In this study the results from a series of calculations are reported that probe the influence of the QM cluster size and the extended framework treatment in ONIOM calculations. This is done by comparing the differences in the structures and
Philip T M Carlsson et al.
Physical chemistry chemical physics : PCCP, 14(45), 15637-15640 (2012-10-24)
Recent studies have suggested that the reaction of stabilised Criegee Intermediates (CIs) with sulfur dioxide (SO(2)), leading to the formation of a carbonyl compound and sulfur trioxide, is a relevant atmospheric source of sulfuric acid. Here, the significance of this

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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