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Sigma-Aldrich

Tris(4-bromphenyl)ammoniumylhexachlorantimonat

technical grade

Synonym(e):

Hexachloroantimonate tris(4-bromophenyl)amine, Magic Blue, Tris(4-bromophenyl)aminium hexachloroantimonate, Tris(p-bromophenyl)aminium hexachloroantimonate(1-), Tris(p-bromophenyl)aminium hexachloroantimonate

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About This Item

Lineare Formel:
(BrC6H4)3NSbCl6
CAS-Nummer:
24964-91-8
Molekulargewicht:
816.48
UNSPSC-Code:
12352101
PubChem Substanz-ID:
24853786
NACRES:
NA.22
Preise und Verfügbarkeit sind derzeit nicht verfügbar.

Qualität

technical grade

Qualitätsniveau

100

Form

powder

mp (Schmelzpunkt)

142 °C (dec.) (lit.)

SMILES String

Cl[Sb-](Cl)(Cl)(Cl)(Cl)Cl.Brc1ccc(cc1)[N+](c2ccc(Br)cc2)c3ccc(Br)cc3

InChI

1S/C18H12Br3N.6ClH.Sb/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18;;;;;;;/h1-12H;6*1H;/q+1;;;;;;;+5/p-6

InChIKey

SDHBPVANTRLAKE-UHFFFAOYSA-H

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Anwendung

Tris(4-bromophenyl)ammoniumyl hexachloroantimonate can be used as a strong oxidant for the chemical doping of conjugated polymers[1]. It can also be used as a catalyst for the deprotection of tert-butyldimethylsilyl and tetrahydropyranyl ethers[2].

Piktogramme

Exclamation markEnvironment
GHS07,GHS09

Signalwort

Warning

Gefahreneinstufungen

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 2

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Gloves

Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

Lot/Batch Number
0000300096
0000300096
MKCV6218
MKBD8523V
MKCQ2982

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Sigma-Aldrich

164682

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Chemical doping of conjugated polymers with the strong oxidant magic blue
Hofmann A, et al.
Advanced Electronic Materials, 6, 2000249-2000249 (2020)
A mild and efficient cleavage of tert-butyldimethylsilyl (TBS) and tetrahydropyranyl (THP) ethers using a catalytic amount of TBPA+ SbCl6
Xu Y, et al.
Tetrahedron Letters, 49, 3634-3637 (2008)
Rachel L Meyer et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 26(44), 9905-9914 (2020-03-21)
The rational control of the electrochemical properties of polyoxovanadate-alkoxide clusters is dependent on understanding the influence of various synthetic modifications on the overall redox processes of these systems. In this work, the electronic consequences of ligand substitution at the heteroion
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Analytica chimica acta, 1107, 107-112 (2020-03-24)
Many important chemical transformations proceed by way of ionic and/or neutral intermediates. Great effort has been expended to understand the mechanism, with only minimum attention given to separate associated ionic and neutral intermediates. Herein, we present a nebulization method followed

Questions

1–2 of 2 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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