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Dokumente

159549

Sigma-Aldrich

4-Brommethyl-benzoesäure

97%

Synonym(e):

α-Brom-p-toluylsäure

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About This Item

Lineare Formel:
BrCH2C6H4CO2H
CAS-Nummer:
6232-88-8
Molekulargewicht:
215.04
Beilstein:
1862870
EG-Nummer:
228-343-3
MDL-Nummer:
MFCD00002567
UNSPSC-Code:
12352100
PubChem Substanz-ID:
24849820
NACRES:
NA.22

Assay

97%

Form

solid

mp (Schmelzpunkt)

224-229 °C (lit.)

SMILES String

OC(=O)c1ccc(CBr)cc1

InChI

1S/C8H7BrO2/c9-5-6-1-3-7(4-2-6)8(10)11/h1-4H,5H2,(H,10,11)

InChIKey

CQQSQBRPAJSTFB-UHFFFAOYSA-N

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Anwendung

4-(Bromomethyl)benzoic acid was used in the chemical modification of 5,10,15,20-tetra(m-hydroxyphenyl)chlorin (temoporfin), second generation photosensitizer. It was also used in the synthesis of 4-(5-arylidene-2,4-dioxothiazolidin-3-yl) methylbenzoic acids.

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Gloves

Analysenzertifikate (COA)

Suchen Sie nach Analysenzertifikate (COA), indem Sie die Lot-/Chargennummer des Produkts eingeben. Lot- und Chargennummern sind auf dem Produktetikett hinter den Wörtern ‘Lot’ oder ‘Batch’ (Lot oder Charge) zu finden.

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4-(Chlormethyl)benzoylchlorid 97%

Sigma-Aldrich

270784

4-(Chlormethyl)benzoylchlorid

3-Brommethylbenzoesäure-methylester 97%

Sigma-Aldrich

648116

3-Brommethylbenzoesäure-methylester

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4-(5-Arylidene-2,4-dioxothiazolidin-3-yl)methylbenzoic acids (2) were synthesized and evaluated in vitro as inhibitors of PTP1B and LMW-PTP, two protein tyrosine phosphatases (PTPs) which act as negative regulators of the metabolic and mitotic signalling of insulin. The synthesis of compounds 2 represents an
Q Yu et al.
Chemical communications (Cambridge, England), 50(81), 12150-12153 (2014-09-02)
LiYF4:Tm(3+)/Yb(3+) upconverting nanoparticles (UCNPs) were functionalized with the second generation photosensitizer 5,10,15,20-tetra(m-hydroxyphenyl)chlorin (m-THPC, Temoporfin, Foscan®). m-THPC was modified using 4-(bromomethyl)benzoic acid, which induced a bathochromic shift of the m-THPC blue absorption peak. The nanoconstruct causes up to 70% cell death
Salvatore Lombardo et al.
Langmuir : the ACS journal of surfaces and colloids, 33(22), 5473-5481 (2017-05-13)
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