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106860

Sigma-Aldrich

Acetylferrocen

95%

Synonym(e):

(Acetylcyclopentadienyl)-cyclopentadienyleisen

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About This Item

Empirische Formel (Hill-System):
C12H12FeO
CAS-Nummer:
1271-55-2
Molekulargewicht:
228.07
EG-Nummer:
215-043-2
MDL-Nummer:
MFCD00001432
UNSPSC-Code:
12161600
PubChem Substanz-ID:
24846743
NACRES:
NA.22

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Qualitätsniveau

100

Assay

95%

Form

solid

Eignung der Reaktion

core: iridium
reagent type: catalyst

mp (Schmelzpunkt)

81-83 °C (lit.)

SMILES String

[Fe].[CH]1[CH][CH][CH][CH]1.CC(=O)[C]2[CH][CH][CH][CH]2

InChI

1S/C7H7O.C5H5.Fe/c1-6(8)7-4-2-3-5-7;1-2-4-5-3-1;/h2-5H,1H3;1-5H;

InChIKey

PHMAOJNZIFULOG-UHFFFAOYSA-N

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Allgemeine Beschreibung

Acetylferrocene is an organometallic compound that can be used as a catalyst and as a starting material for the synthesis of complex organometallic compounds. [1]

Anwendung

Acetylferrocene can be used as:
  • A Precursor to synthesize 1-ferrocenylethanol by reduction in the presence of sodium borohydride.[2]
  • An electroactive compound along with MgO nanoparticles to modify carbon paste electrode (CPE) that can be used to determine L-cysteine.[3]

Piktogramme

Skull and crossbones
GHS06

Signalwort

Danger

H-Sätze

H300 + H310

Gefahreneinstufungen

Acute Tox. 1 Dermal - Acute Tox. 2 Oral

Lagerklassenschlüssel

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 2

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Analysenzertifikate (COA)

Lot/Batch Number
WXBF1816V
WXBD9418V
STBJ5703
STBG8062
STBF0032V

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In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Electrocatalytic determination of L-cysteine in the presence of tryptophan using carbon paste electrode modified with MgO nanoparticles and acetylferrocene
Gupta VK, et al.
International Journal of Electrochemical Science, 13, 4309-4318 (2018)
Sunita Yadav et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 78(1), 298-306 (2010-12-21)
Biological important complexes of boron(III) derived from 1-acetylferrocenehydrazinecarboxamide (L1H), 1-acetylferrocenehydrazinecarbothioamide (L2H) and 1-acetylferrocene carbodithioic acid (L3H) have been prepared and investigated using a combination of microanalytical analysis, melting point, electronic, IR, 1H NMR and 13C NMR spectral studies, cyclic voltammetry
Y N Vashisht Gopal et al.
Archives of biochemistry and biophysics, 376(1), 229-235 (2000-03-24)
Topoisomerase II is a major molecular target for a number of DNA-binding anticancer drugs. In the present study, we report topoisomerase II inhibition and anticancer activity by four substituted ferrocene derivatives which do not bind to DNA. The first derivative
Jeremie Brichet et al.
Journal of enzyme inhibition and medicinal chemistry, 35(1), 622-628 (2020-02-11)
A series of bio-organometallic-hydrazones of the general formula [{(η5-C5H4)-C(R)=N-N(H)-C6H4-4-SO2NH2}]MLn(MLn = Re(CO)3, Mn(CO)3, FeCp; R=H, CH3) were prepared by reaction of formyl/acetyl organometallic precursors with 4-hydrazino-benzenesulphonamide. All compounds were characterized by conventional spectroscopic techniques (infra-red, 1H and 13C NMR, mass spectrometry and elemental
Martin Bertau et al.
Bioorganic & medicinal chemistry, 12(11), 2973-2983 (2004-05-15)
The bioavailability of lipophilic substrates is critical for biotransformations with isolated enzymes as well as with whole cells. With the example of a series of lipophilic ketones the suitability of saccharides as potent solubilisers for highly lipophilic substrates was demonstrated.
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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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