668540

(2S,5S)-(–)-5-Benzyl-3-methyl-2-(5-methyl-2-furyl)-4-imidazolidinone

95%

• Synonyme(s) : (2S,5S)-3-Methyl-2-(5-methyl-2-furanyl)-5-(phenylmethyl)-4-imidazolidinone
• Formule empirique (notation de Hill): C₁₆H₁₈N₂O₂
• Numéro CAS: 415678-40-9
• Poids moléculaire : 270.33
• Numéro MDL: MFCD08457653
• Code UNSPSC : 12352005
• ID de substance PubChem : 24884991
• Nomenclature NACRES : NA.22

Propriétés

• Pureté: 95%
• Indice de réfraction: n20/D 1.5598
• Chaîne SMILES: CN1[C@H](N[C@@H](Cc2ccccc2)C1=O)c3ccc(C)o3
• InChI: 1S/C16H18N2O2/c1-11-8-9-14(20-11)15-17-13(16(19)18(15)2)10-12-6-4-3-5-7-12/h3-9,13,15,17H,10H2,1-2H3/t13-,15-/m0/s1
• Clé InChI: IQIMPHPFMHVWBZ-ZFWWWQNUSA-N

Description

Application

Catalyst for:

• Enantioselective organocatalytic transfer hydrogenation of cycloalkenones with tert-Bu Hantzsch ester as source of hydrogen
• Alkylation of indoles with an α,β-disubstituted α,β-unsaturated aldehyde in the enantioselective preparation of a selective serotonin reuptake inhibitor
• MacMillan reaction

Highly selective organocatalyst for the Diels-Alder reaction with simple α,β−unsaturated ketones.

Informations légales

U.S. Pat. 6,369,243 and related patents apply. For research purposes only.

Informations sur la sécurité

• Pictogrammes: GHS06
• Mention d'avertissement: Danger
• Mentions de danger: H301,H315,H319,H335
• Conseils de prudence: P261 - P264 - P271 - P301 + P310 - P302 + P352 - P305 + P351 + P338
• Classification des risques: Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Organes cibles: Respiratory system
• Code de la classe de stockage: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): >230.0 °F
• Point d'éclair (°C): > 110 °C
• Équipement de protection individuelle: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges