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A30702

Sigma-Aldrich

Allyl chloride

reagent grade, 98%

Synonyme(s) :

3-Chloro-1-propene, Chlorallylene

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500 ML
57,60 $
1 L
94,00 $
2.5 L
219,00 $

57,60 $

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Changer de vue
500 ML
57,60 $
1 L
94,00 $
2.5 L
219,00 $

About This Item

Formule linéaire :
CH2=CHCH2Cl
Numéro CAS:
107-05-1
Poids moléculaire :
76.52
Beilstein:
635704
Numéro CE :
203-457-6
Numéro MDL:
MFCD00000984
Code UNSPSC :
12352100
ID de substance PubChem :
57653821
Nomenclature NACRES :
NA.22

57,60 $

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Devis pour commande en gros

Qualité

reagent grade

Niveau de qualité

200

Densité de vapeur

2.6 (vs air)

Pression de vapeur

20.58 psi ( 55 °C)
5.71 psi ( 20 °C)

Essai

98%

Forme

liquid

Limite d'explosivité

11.2 %

Indice de réfraction

n20/D 1.414 (lit.)

pb

44-46 °C (lit.)

Pf

−130 °C (lit.)

Densité

0.939 g/mL at 25 °C (lit.)

Température de stockage

2-8°C

Chaîne SMILES 

ClCC=C

InChI

1S/C3H5Cl/c1-2-3-4/h2H,1,3H2

Clé InChI

OSDWBNJEKMUWAV-UHFFFAOYSA-N

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Catégories apparentées

Application

Allyl chloride can be used as a reactant to prepare:
  • 1-Allyl-2-alkynylbenzene derivatives through allylalkynylation of in situ generated benzynes.[1]
  • α,ω-Difunctional intermediates by reacting with fatty acid methyl esters using ruthenium catalysts.[2]
  • Homoallylic alcohols through Sn/I2 catalyzed Barbier-type allylation reactions of carbonyl compounds.[3]

Autres remarques

The article number A30702-4X1L will be discontinued. Please order the single bottle A30702-1L which is physically identical with the same exact specifications.

Mention d'avertissement

Danger

Classification des risques

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Muta. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

Organes cibles

Nervous system,Liver,Kidney, Respiratory system

Code de la classe de stockage

3 - Flammable liquids

Classe de danger pour l'eau (WGK)

WGK 2

Point d'éclair (°F)

-25.6 °F

Point d'éclair (°C)

-32 °C

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves

Faites votre choix parmi les versions les plus récentes :

Certificats d'analyse (COA)

Lot/Batch Number
SDBB0808
STBL0672
STBL2012
STBK6237
SHBP5704

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Sn/I2 Mediated allylation of carbonyl compounds with allyl (crotyl) halide in water
Zhou Y, et al.
ARKIVOC (Gainesville, FL, United States), 11(1), 142-153 (2008)
Airong Xu et al.
Scientific reports, 9(1), 11518-11518 (2019-08-10)
The utilization of cellulose in industrial applicat is of great significance to sustainable development of human society and reducing dependence on dwindling fossil resources. Nevertheless, this utilization of cellulose has actually been limited due to its insolubilization. Here, novel solvents
Palladium-Catalyzed Allylalkynylation of Benzynes: A Highly Efficient Route to Substituted 1-Allyl-2-alkynylbenzenes
Jeganmohan M and Cheng C-H
Organic Letters, 6(16), 2821-2824 (2004)
Airong Xu et al.
Polymers, 11(5) (2019-05-15)
Cellulose is the most abundant natural biopolymer, with unique properties such as biodegradability, biocompability, nontoxicity, and so on. However, its extensive application has actually been hindered, because of its insolubility in water and most solvents. Herein, highly efficient cellulose solvents
Cross-metathesis reactions of allyl chloride with fatty acid methyl esters: Efficient synthesis of a, ?-difunctional chemical intermediates from renewable raw materials.
Jacobs T, et al.
Applied Catalysis A: General, 353(1), 32-35 (2009)
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Questions

1–2 of 2 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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